methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate

Base Information

• Chemical Name: methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate
• CAS No.: 142066-75-9
• Molecular Formula: C₂₂H₃₁N₃O₄
• Molecular Weight: 401.506

Synonyms:methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate

Chemical Property of methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate

Chemical Property:

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Safty Information:

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Technology Process of methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate

There total 2 articles about methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

4-phenyl-semicarbazide (537-47-3) + methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-formyl-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate (142066-74-8) → methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate (142066-75-9)

Guidance literature:

With sodium cyanoborohydride; acetic acid; In methanol; for 0.333333h; Ambient temperature;

DOI:10.1021/jm00094a017

Reference yield: 52.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoic acid (142066-76-0) → methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate (142066-75-9)

Guidance literature:

In diethyl ether;

DOI:10.1021/jm00094a017

Reference yield: 51.0%

methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate (142066-75-9) → <1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoic acid (142066-76-0)

Guidance literature:

With potassium carbonate; In methanol; for 0.666667h; Heating;

DOI:10.1021/jm00094a017

upstream raw materials:

diazomethane

<1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoic acid

4-phenyl-semicarbazide

methyl <1S-(1α,2β(Z),3α,4α)>-7-<3-formyl-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate

Downstream raw materials:

<1S-(1α,2β(Z),3α,4α)>-7-<3-<<2-<(phenylamino)carbonyl>hydrazino>methyl>-5-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoic acid

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