2,4-Di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosylbromid

Base Information

• Chemical Name: 2,4-Di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosylbromid
• CAS No.: 77852-50-7
• Molecular Formula: C₂₃H₂₈BrNO₄
• Molecular Weight: 462.384
• Mol file: 77852-50-7.mol

Synonyms:2,4-Di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosylbromid

Chemical Property of 2,4-Di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosylbromid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4-Di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosylbromid

There total 1 articles about 2,4-Di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosylbromid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-O-Acetyl-2,4-di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-D-glucopyranose (77852-49-4,77852-53-0) → 2,4-Di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosylbromid (77852-50-7)

Guidance literature:

With titanium(IV) bromide; In ethyl acetate; toluene; for 5h;

DOI:10.1002/cber.19811140303

Reference yield: 57.5%

2,4-Di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosylbromid (77852-50-7) + 1,3,2',6'-Tetrakis-N-(benzyloxycarbonyl)sisamin (69992-04-7) → 1,3,2',6'-Tetrakis-N-(benzyloxycarbonyl)-6-O-<2,4-di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosyl>sisamin (77852-51-8,77881-76-6) + C67H75N5O16 (77852-51-8,77881-76-6)

Guidance literature:

With 4 A molecular sieve; mercury(II) cyanide; In tetrahydrofuran; at 45 - 50 ℃; for 48h;

DOI:10.1002/cber.19811140303

upstream raw materials:

1-O-Acetyl-2,4-di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-D-glucopyranose

Downstream raw materials:

1,3,2',6'-Tetrakis-N-(benzyloxycarbonyl)-6-O-<2,4-di-O-benzyl-3,6-didesoxy-3-(N-methylacetamido)-α-D-glucopyranosyl>sisamin

C₆₇H₇₅N₅O₁₆