mesityl(4-(trifluoromethyl)phenyl)-λ³-iodanyl trifluoromethanesulfonate

Base Information

• Chemical Name: mesityl(4-(trifluoromethyl)phenyl)-λ³-iodanyl trifluoromethanesulfonate
• CAS No.: 1232133-62-8
• Molecular Formula: CF₃O₃S*C₁₆H₁₅F₃I
• Molecular Weight: 540.265
• Mol file: 1232133-62-8.mol

Synonyms:mesityl(4-(trifluoromethyl)phenyl)-λ³-iodanyl trifluoromethanesulfonate

Chemical Property of mesityl(4-(trifluoromethyl)phenyl)-λ³-iodanyl trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mesityl(4-(trifluoromethyl)phenyl)-λ³-iodanyl trifluoromethanesulfonate

There total 6 articles about mesityl(4-(trifluoromethyl)phenyl)-λ³-iodanyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

trifluorormethanesulfonic acid (1493-13-6) + 4-Iodobenzotrifluoride (455-13-0) + 1,3,5-trimethyl-benzene (108-67-8) → mesityl(4-(trifluoromethyl)phenyl)-λ3-iodanyl trifluoromethanesulfonate (1232133-62-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In 1,2-dichloro-ethane; at 20 ℃; for 0.0166667h; Inert atmosphere; Flow reactor; Sonication;

DOI:10.1021/acs.joc.7b01346

Reference yield:

4-Iodobenzotrifluoride (455-13-0) + 1,3,5-trimethyl-benzene (108-67-8) → mesityl(4-(trifluoromethyl)phenyl)-λ3-iodanyl trifluoromethanesulfonate (1232133-62-8)

Guidance literature:

With trifluorormethanesulfonic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1016/j.jfluchem.2015.09.015

Reference yield:

(mesityl)(4-iodophenyl)iodonium tetrafluoroborate → mesityl(4-(trifluoromethyl)phenyl)-λ3-iodanyl trifluoromethanesulfonate (1232133-62-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: tetrabutylammonium triphenyldifluorosilicate; copper(I) thiophene-2-carboxylate / N,N-dimethyl-formamide / 0.08 h / 20 °C / Inert atmosphere

1.2: 0.08 h / 20 °C / Inert atmosphere

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 0 - 20 °C

With copper(I) thiophene-2-carboxylate; 3-chloro-benzenecarboperoxoic acid; tetrabutylammonium triphenyldifluorosilicate; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1016/j.jfluchem.2016.04.008

upstream raw materials:

4-Iodobenzotrifluoride

1,3,5-trimethyl-benzene

trifluorormethanesulfonic acid

4-trifluoromethylphenylboronic acid

Downstream raw materials:

1,4-bis(trifluoromethyl)benzene

4-(4-trifluoromethylphenyl)morpholine

4-(3-(trifluoromethyl)phenyl)morpholine

1-phenyl-2-(4-(trifluoromethyl)phenyl)ethan-1-one