(η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate

Base Information

Chemical Name:(η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate
CAS No.:61003-34-7
Molecular Formula:C₃₂H₄₆P₃Ru*F₆P
Molecular Weight:769.673
Hs Code.:

Synonyms:(η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate

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Chemical Property of (η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate

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Technology Process of (η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate

There total 1 articles about (η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 64722-25-4
(η-cyclo-octa-1,5-diene)tris(N,N-dimethylhydrazine)hydridoruthenium(II) hexafluorophosphate

: 672-66-2
Dimethyl(phenyl)phosphine

: 61003-34-7
(η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate

Guidance literature:: In methanol; Ar-atmosphere; addn. of 3.1 equiv. of phosphine to Ru-complex soln. (20°C, pptn.); filtration, recrystn. (CH2Cl2/EtOH, 0°C); elem. anal.;
DOI:10.1039/DT9780001032

Reference yield: 75.0%

: 61003-34-7
(η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate

: 82640-98-0
(η3-cyclooctenyl)tris(dimethylphenylphosphine)ruthenium(II) hexafluorophosphate

Guidance literature:: In ethanol; The suspn. of complex in EtOH was heated under reflux for 15 min (N2 atm.); cooled to room temp.,then to 0°C;;

Reference yield: 70.0%

: 1,3,5,7-cycloocatetraene

: 61003-34-7
(η-cyclo-octa-1,5-diene)tris(dimethylphenylphosphine)hydridoruthenium hexafluorophosphate

: Ru(C₈H₉)(P(CH₃)2C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=(Ru(C₈H₉)(P(CH₃)2C₆H₅)3)PF₆

Guidance literature:: In methanol; a suspn. of Ru-complex in MeOH containing an excess of cyclooctatetraene was heated to 60°C; ppt. was collected; anal. pure;
DOI:10.1016/0022-328X(84)80646-4