lithio α-chloromethyl phenyl sulfoxide

Base Information

• Chemical Name: lithio α-chloromethyl phenyl sulfoxide
• CAS No.: 41103-65-5
• Molecular Formula: C₇H₆ClLiOS
• Molecular Weight: 180.584
• Mol file: 41103-65-5.mol

Synonyms:lithio α-chloromethyl phenyl sulfoxide

Chemical Property of lithio α-chloromethyl phenyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of lithio α-chloromethyl phenyl sulfoxide

There total 1 articles about lithio α-chloromethyl phenyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ lithio α-chloromethyl phenyl sulfoxide (41103-65-5)

Guidance literature:

Chlormethyl-phenylsulfoxid, Butyl-lithium;

DOI:10.1021/ja01032a046

Reference yield: 73.0%

lithio α-chloromethyl phenyl sulfoxide (41103-65-5) + trans-3-penten-2-one (3102-33-8) → (E)-1-Benzenesulfinyl-1-chloro-2-methyl-pent-3-en-2-ol (121000-78-0)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; at -78 ℃;

DOI:10.1246/cl.1989.163

Reference yield: 72.0%

lithio α-chloromethyl phenyl sulfoxide (41103-65-5) + 2-((S)-2-Benzyloxy-3-iodo-propyl)-5,5-dimethyl-[1,3]dioxane (82130-81-2) → 2-((S)-4-Benzenesulfinyl-2-benzyloxy-4-chloro-butyl)-5,5-dimethyl-[1,3]dioxane (82130-82-3)

Guidance literature:

DOI:10.1016/S0040-4039(00)86913-0

Downstream raw materials:

1-benzenesulfinyl-1-chloro-octan-2-ol

1-chloro-1-phenylsulfinylhexan-2-ol

1-benzenesulfinyl-1-chloro-nonan-2-ol

1-benzenesulfinyl-1-chloro-pentan-2-ol