Ni(CO)(CH₂CHCN(Si(CH₃)2CH₂P(C₆H₅)2)OSi(CH₃)2CH₂P(C₆H₅)2)

Base Information

• Chemical Name: Ni(CO)(CH₂CHCN(Si(CH₃)2CH₂P(C₆H₅)2)OSi(CH₃)2CH₂P(C₆H₅)2)
• CAS No.: 92097-64-8
• Molecular Formula: C₃₄H₃₉NNiO₂P₂Si₂
• Molecular Weight: 670.498
• Mol file: 92097-64-8.mol

Synonyms:Ni(CO)(CH₂CHCN(Si(CH₃)2CH₂P(C₆H₅)2)OSi(CH₃)2CH₂P(C₆H₅)2)

Chemical Property of Ni(CO)(CH₂CHCN(Si(CH₃)2CH₂P(C₆H₅)2)OSi(CH₃)2CH₂P(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(CO)(CH₂CHCN(Si(CH₃)2CH₂P(C₆H₅)2)OSi(CH₃)2CH₂P(C₆H₅)2)

There total 4 articles about Ni(CO)(CH₂CHCN(Si(CH₃)2CH₂P(C₆H₅)2)OSi(CH₃)2CH₂P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ni(CHCH2){N(Si(CH3)2CH2P(C6H5)2)2} → Ni(CO)(CH2CHCN(Si(CH3)2CH2P(C6H5)2)OSi(CH3)2CH2P(C6H5)2) (92097-64-8)

Guidance literature:

With carbon monoxide; In toluene; a soln. of Ni-complex in toluene was stirred under 1 atm of CO at room temp. for 3 h, the excess of CO was removed in vacuo and the soln. stirred under partial vac. for 7 d; solvent was removed, residue recrystd. from hexane; elem. anal.;

DOI:10.1021/ja00335a022

Reference yield:

Ni(CHCH2){N(Si(CH3)2CH2P(C6H5)2)2} → Ni(CO)2(CH2CHCN(Si(CH3)2CH2P(C6H5)2)OSi(CH3)2CH2P(C6H5)2) (92097-61-5) + Ni(CO)(CH2CHCN(Si(CH3)2CH2P(C6H5)2)OSi(CH3)2CH2P(C6H5)2) (92097-64-8)

Guidance literature:

With carbon monoxide; In toluene; a soln. of Ni-complex in toluene was stirred under 1 atm of CO at room temp. for 3 h; di- and monocarbonyl complexes were formed in ca. 9:1 ratio; solvent was removed in vacuo, residue taken up in min. hexanes, crystals were filtered and washed with cold hexane; major product (dicarbonyl complex) was not obtained in anal. pure form;

DOI:10.1021/ja00335a022

Reference yield:

Ni(CO)2(CH2CHCN(Si(CH3)2CH2P(C6H5)2)OSi(CH3)2CH2P(C6H5)2) (92097-61-5) → Ni(CO)(CH2CHCN(Si(CH3)2CH2P(C6H5)2)OSi(CH3)2CH2P(C6H5)2) (92097-64-8)

Guidance literature:

In not given; byproducts: CO; dicarbonyl complex slowly loses CO ligand in soln. under N2 or under vac. to produce η2-vinyl complex;

DOI:10.1021/ja00335a022

upstream raw materials:

Ni(CO)2(CH₂CHCN(Si(CH₃)2CH₂P(C₆H₅)2)OSi(CH₃)2CH₂P(C₆H₅)2)

Downstream raw materials:

Ni(CO)2(CH₂CHCN(Si(CH₃)2CH₂P(C₆H₅)2)OSi(CH₃)2CH₂P(C₆H₅)2)