C₂₆H₄₀O₇

Base Information

• Chemical Name: C₂₆H₄₀O₇
• CAS No.: 1388153-41-0
• Molecular Formula: C₂₆H₄₀O₇
• Molecular Weight: 464.599
• Mol file: 1388153-41-0.mol

Synonyms:C₂₆H₄₀O₇

Chemical Property of C₂₆H₄₀O₇

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₆H₄₀O₇

There total 30 articles about C₂₆H₄₀O₇ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C48H72O7Si2 (1388153-01-2) → C26H40O7 (1388153-41-0)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 - 20 ℃; for 2.5h;

DOI:10.1021/ja305864z

Reference yield:

C48H72O7Si2 (1388152-99-5) → C26H40O7 (1388153-41-0)

Guidance literature:

Multi-step reaction with 3 steps

1: N-Bromosuccinimide / acetonitrile / 1 h / 0 - 20 °C

2: 2,2'-azobis(isobutyronitrile); triphenylstannane / toluene / 0.5 h / 110 °C

3: tetrabutyl ammonium fluoride / tetrahydrofuran / 2.5 h / 0 - 20 °C

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); triphenylstannane; tetrabutyl ammonium fluoride; In tetrahydrofuran; toluene; acetonitrile;

DOI:10.1021/ja305864z

Reference yield:

C24H36O3Si (1388153-35-2) → C26H40O7 (1388153-41-0)

Guidance literature:

Multi-step reaction with 8 steps

1.1: pyridinium p-toluenesulfonate / dichloromethane / 2 h / 20 °C

2.1: diisobutylaluminium hydride / hexane; dichloromethane / 2.5 h / -78 - -40 °C / Inert atmosphere

3.1: 1H-imidazole; iodine; triphenylphosphine / tetrahydrofuran / 0.5 h / 20 °C

4.1: tert.-butyl lithium; 9-methoxy-9-BBN / diethyl ether; hexane; pentane / 1.08 h / -78 - 20 °C / Inert atmosphere

4.2: 2 h / 50 °C / Inert atmosphere

5.1: Allyl ether; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 0 - 20 °C / pH 7 / aq. phosphate buffer

6.1: N-Bromosuccinimide / acetonitrile / 1 h / 0 - 20 °C

7.1: 2,2'-azobis(isobutyronitrile); triphenylstannane / toluene / 0.5 h / 110 °C

8.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2.5 h / 0 - 20 °C

With 1H-imidazole; N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); Allyl ether; triphenylstannane; tetrabutyl ammonium fluoride; iodine; tert.-butyl lithium; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; 9-methoxy-9-BBN; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; toluene; acetonitrile; pentane; 4.1: Suzuki-Miyaura coupling / 4.2: Suzuki-Miyaura coupling;

DOI:10.1021/ja305864z

upstream raw materials:

C₁₄H₁₈O₃

C₃₄H₄₃NO₅Si

C₂₄H₃₆O₃Si

C₃₂H₄₄O₄Si

Downstream raw materials:

C₅₉H₆₄O₇