(1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime

Base Information

Chemical Name:(1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime
CAS No.:745801-33-6
Molecular Formula:C₁₆H₂₁NOS
Molecular Weight:275.415
Hs Code.:

Synonyms:(1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime

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Technology Process of (1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime

There total 4 articles about (1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 214599-31-2
(1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one

: 745801-33-6
(1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime

Guidance literature:: With pyridine; hydroxylamine hydrochloride; In ethanol; Heating;
DOI:10.1039/b402805h

Reference yield:

: 3144-16-9,61380-66-3
(1S)-10-camphorsulfonic acid

: 745801-33-6
(1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / SOCl₂ / 2 h / Heating

2: 88 percent / triphenylphosphine / H₂O; dioxane / 2 h / Heating

3: 72 percent / EtONa; PPh₃ / palladium acetate / ethanol / 24 h / Heating

4: 89 percent / NH₂OH*HCl; pyridine / aq. ethanol / Heating

With pyridine; thionyl chloride; hydroxylamine hydrochloride; sodium ethanolate; triphenylphosphine; palladium diacetate; In 1,4-dioxane; ethanol; water;
DOI:10.1039/b402805h

Reference yield:

: 54984-43-9,77026-99-4
(1S,4R)-camphor-10-thiol

: 745801-33-6
(1S,4R)-1-phenylsulfanylmethyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one oxime

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / EtONa; PPh₃ / palladium acetate / ethanol / 24 h / Heating

2: 89 percent / NH₂OH*HCl; pyridine / aq. ethanol / Heating

With pyridine; hydroxylamine hydrochloride; sodium ethanolate; triphenylphosphine; palladium diacetate; In ethanol;
DOI:10.1039/b402805h