[bis(triphenylphosphoranylidene)ammonium][NiCl(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]

Base Information

• Chemical Name: [bis(triphenylphosphoranylidene)ammonium][NiCl(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]
• CAS No.: 956107-44-1
• Molecular Formula: C₂₇H₃₇ClNiPS₃Si₃*C₃₆H₃₀NP₂
• Molecular Weight: 1205.75

Synonyms:[bis(triphenylphosphoranylidene)ammonium][NiCl(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]

Chemical Property of [bis(triphenylphosphoranylidene)ammonium][NiCl(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]

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Technology Process of [bis(triphenylphosphoranylidene)ammonium][NiCl(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))]

There total 1 articles about [bis(triphenylphosphoranylidene)ammonium][NiCl(P(o-C₆H₃-3-SiMe₃-2-S)2(o-C₆H₃-3-SiMe₃-2-SH))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

[bis(triphenylphosphoranylidene)ammonium][NiCl4] + 2,2',2-trimercapto-3,3',3-tris(trimethylsilyl)triphenylphosphine (119327-24-1) → [bis(triphenylphosphoranylidene)ammonium][NiCl(P(o-C6H3-3-SiMe3-2-S)2(o-C6H3-3-SiMe3-2-SH))] (956107-44-1) + [Ni(P(o-C6H3-3-SiMe3-2-S)2(o-C6H3-3-SiMe3-2-SH))]2 (956107-45-2)

Guidance literature:

In tetrahydrofuran; acetonitrile; byproducts: N(P(C6H5)3)2Cl; (N2); ligand and Ni complex dissolved in THF/MeCN, stirred at ambient temp. for 30 min; pptd. (hexane), dissolved in THF, filtered, pptd. (hexane);

DOI:10.1021/ic700719h

Reference yield: 69.0%

[bis(triphenylphosphoranylidene)ammonium][NiCl(P(o-C6H3-3-SiMe3-2-S)2(o-C6H3-3-SiMe3-2-SH))] (956107-44-1) → [Ni(Cl)(P(C6H3-3-SiMe3-2-S)3)]- (922725-12-0)

Guidance literature:

With 2,4,6-tri-tert-butyl phenoxyl radical; In tetrahydrofuran; at 23 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1021/jacs.0c00712

upstream raw materials:

2,2',2-trimercapto-3,3',3-tris(trimethylsilyl)triphenylphosphine

Downstream raw materials:

[Ni(Cl)(P(C₆H₃-3-SiMe₃-2-S)₃)]^-

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