1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethene

Base Information

• Chemical Name: 1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethene
• CAS No.: 544696-81-3
• Molecular Formula: C₁₇H₁₃O₃ReS
• Molecular Weight: 483.561
• Mol file: 544696-81-3.mol

Synonyms:1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethene

Chemical Property of 1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethene

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethene

There total 1 articles about 1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

decacarbonyldirhenium(0) (14285-68-8) + 6-methyl-6-(4'-methylthiophenyl)fulvene (544476-27-9) → 1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethane (544696-84-6) + 1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethene (544696-81-3)

Guidance literature:

In 1,2,5-trimethyl-benzene; (Ar); using Schlenk techniques; addn. of Re2(CO)10 (0.2 mmol) to soln. of CH3SC6H4C(CH3)C5H4 (0.8 mmol) in mesitylene (1 ml); quickly immersing in an oil bath at 180°C; reflux for 3 h; cooling to room temp., removal of mesitylene under vac., flash chromy. (petroleum ether-CH2Cl2, 85:15);

DOI:10.1016/S0022-328X(02)02090-9

Reference yield: 96.0%

1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethene (544696-81-3) → 1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethane (544696-84-6)

Guidance literature:

With triethylsilane; trifluoroacetic acid; In dichloromethane; (Ar); using Schlenk techniques; addn. of trifluoroacetic acid to soln. of Re(CO)3(C5H4C(CH2)C6H4SMe) and Et3SiH; stirring for 24 h at room temp.; diluion with CH2Cl2, pouring in a satd. soln. of NaHCO3; drying of org. layer over MgSO4, concn., flash chromy. (petroleum ether-CH2Cl2, 85:15);

DOI:10.1016/S0022-328X(02)02090-9

upstream raw materials:

decacarbonyldirhenium⁽⁰⁾

6-methyl-6-(4'-methylthiophenyl)fulvene

Downstream raw materials:

1-cyclopentadienyltricarbonylrhenium-1-(4'-methylthiophenyl)ethane