(Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester

Base Information

Chemical Name:(Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester
CAS No.:112497-30-0
Molecular Formula:C₁₇H₃₂O₃Si
Molecular Weight:312.525
Hs Code.:

Synonyms:(Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester

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Chemical Property of (Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester

Chemical Property:

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Technology Process of (Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester

There total 6 articles about (Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 112497-28-6
((E)-1-Cyclohexyl-3-trimethylsilanyl-allyloxy)-acetic acid isopropyl ester

: 112497-30-0
(Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester

Guidance literature:: With zirconocene dichloride; lithium diisopropyl amide; Yield given. Multistep reaction;
DOI:10.1016/S0040-4039(01)80994-1

Reference yield:

: 133216-88-3,112497-25-3
(+/-)-1-cyclohexyl-3-(trimethylsilyl)-2-propynol

: 112497-30-0
(Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / Red-al

4: 1) LDA, 2) Cp₂ZrCl₂

With zirconocene dichloride; sodium bis(2-methoxyethoxy)aluminium dihydride; lithium diisopropyl amide;
DOI:10.1016/S0040-4039(01)80994-1

Reference yield:

: ((E)-1-Cyclohexyl-3-trimethylsilanyl-allyloxy)-acetic acid

: 112497-30-0
(Z)-(2R,3R)-5-Cyclohexyl-2-hydroxy-3-trimethylsilanyl-pent-4-enoic acid isopropyl ester

Guidance literature:: Multi-step reaction with 2 steps

2: 1) LDA, 2) Cp₂ZrCl₂

With zirconocene dichloride; lithium diisopropyl amide;
DOI:10.1016/S0040-4039(01)80994-1