C₂₆H₃₃FO₄Si

Base Information

Chemical Name:C₂₆H₃₃FO₄Si
CAS No.:1373313-85-9
Molecular Formula:C₂₆H₃₃FO₄Si
Molecular Weight:456.63
Hs Code.:

C<sub>26</sub>H<sub>33</sub>FO<sub>4</sub>Si

Synonyms:C₂₆H₃₃FO₄Si

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Chemical Property of C₂₆H₃₃FO₄Si

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Technology Process of C₂₆H₃₃FO₄Si

There total 12 articles about C₂₆H₃₃FO₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.6%

: 1373313-83-7
(2R,3R,4R)-2,3-(O-isopropylidenedioxy)-4-[2-(tert-butyldiphenylsilyloxy)ethyl]-4-cyclopentan-1-one

: 1373313-85-9
C₂₆H₃₃FO₄Si

Guidance literature:: (2R,3R,4R)-2,3-(O-isopropylidenedioxy)-4-[2-(tert-butyldiphenylsilyloxy)ethyl]-4-cyclopentan-1-one; With triethylamine; lithium hexamethyldisilazane; In tetrahydrofuran; at -78 - 20 ℃; for 4h; Inert atmosphere;

With sodium hydrogencarbonate; Selectfluor; In acetonitrile; at 0 - 20 ℃; for 3h;
DOI:10.1021/ol300667q

Reference yield:

: 141436-58-0,126113-84-6
(-)-(1R)-1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol

: 1373313-85-9
C₂₆H₃₃FO₄Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: sodium periodate / dichloromethane / 1 h / 0 - 20 °C

2.1: n-butyllithium; lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

2.2: 12.5 h / -78 - 20 °C / Inert atmosphere

2.3: Inert atmosphere

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 0 - 20 °C

4.1: Grubbs catalyst first generation / dichloromethane / 24 h

5.1: tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere

6.1: sodium perborate tetrahydrate / tetrahydrofuran; water / 15 h / 20 °C / Inert atmosphere

7.1: 1H-imidazole / dichloromethane / 0.5 h / -10 - 0 °C

8.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 0 - 20 °C / Inert atmosphere; Molecular sieve

9.1: palladium 10% on activated carbon; hydrogen / methanol / 48 h / 20 °C

10.1: triethylamine; lithium hexamethyldisilazane / tetrahydrofuran / 4 h / -78 - 20 °C / Inert atmosphere

10.2: 3 h / 0 - 20 °C

With 1H-imidazole; Grubbs catalyst first generation; sodium periodate; n-butyllithium; tetrapropylammonium perruthennate; sodium perborate tetrahydrate; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; 4-methylmorpholine N-oxide; triethylamine; lithium hexamethyldisilazane; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1021/ol300667q

Reference yield:

: 67814-68-0,70266-87-4,76249-50-8,76249-51-9,93451-15-1,4099-88-1
2,3-O-isopropylidene-D-ribofuranose

: 1373313-85-9
C₂₆H₃₃FO₄Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: tetrahydrofuran / 6 h / -78 - 20 °C

1.2: 0 °C

2.1: sodium periodate / dichloromethane / 1 h / 0 - 20 °C

3.1: n-butyllithium; lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

3.2: 12.5 h / -78 - 20 °C / Inert atmosphere

3.3: Inert atmosphere

4.1: Grubbs catalyst first generation / dichloromethane / 24 h

5.1: tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere

6.1: sodium perborate tetrahydrate / tetrahydrofuran; water / 15 h / 20 °C / Inert atmosphere

7.1: 1H-imidazole / dichloromethane / 0.5 h / -10 - 0 °C

8.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 0 - 20 °C / Inert atmosphere; Molecular sieve

9.1: palladium 10% on activated carbon; hydrogen / methanol / 48 h / 20 °C

10.1: triethylamine; lithium hexamethyldisilazane / tetrahydrofuran / 4 h / -78 - 20 °C / Inert atmosphere

10.2: 3 h / 0 - 20 °C

With 1H-imidazole; Grubbs catalyst first generation; sodium periodate; n-butyllithium; tetrapropylammonium perruthennate; sodium perborate tetrahydrate; palladium 10% on activated carbon; hydrogen; 4-methylmorpholine N-oxide; triethylamine; lithium hexamethyldisilazane; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1021/ol300667q