(1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate

Base Information

Chemical Name:(1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate
CAS No.:172840-94-7
Molecular Formula:C₃₅H₄₇NO₅S
Molecular Weight:593.828
Hs Code.:

(1R,2R,3S,4S)-<3-<N-benzenesulfonyl-N-(3,5-dimethylphenyl)-amino>-2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate

Synonyms:(1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate

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Chemical Property of (1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate

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Technology Process of (1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate

There total 6 articles about (1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 594-19-4
tert.-butyl lithium

: 170117-11-0
(1R,2R,3S,4S)-<3--2-bornyl>-2-oxo-cyclohexenecarboxylate

: 172840-94-7
(1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate

Guidance literature:: With copper(l) iodide; In tetrahydrofuran; pentane; at -78 ℃; for 2h;
DOI:10.1016/0040-4020(95)00676-Y

Reference yield: 26.0%

: 170117-11-0
(1R,2R,3S,4S)-<3--2-bornyl>-2-oxo-cyclohexenecarboxylate

: (1R,2R,3S,4S)-<3--2-bornyl>-(6R)-6-cyano-2-hydroxy-cyclohexenecarboxylate

: 172840-94-7
(1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 2h;
DOI:10.1016/0040-4020(95)00676-Y

Reference yield:

: 87360-02-9
N-(3,5-Dimethyl-phenyl)-N-((1S,2S,3R,4R)-3-hydroxy-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-benzenesulfonamide

: 172840-94-7
(1R,2R,3S,4S)-<3--2-bornyl>-(1S,6R)-6-tert-butyl-2-oxo-cyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 94 percent / DMAP / toluene / 48 h / Heating

2: pyridine / CH₂Cl₂ / 2 h / 20 °C

3: 91 percent / mCPBA / CH₂Cl₂ / 2 h / 20 °C

4: 66 percent / CuI / tetrahydrofuran; pentane / 2 h / -78 °C

With pyridine; dmap; copper(l) iodide; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; toluene; pentane;
DOI:10.1016/0040-4020(95)00676-Y