8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid

Base Information

• Chemical Name: 8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid
• CAS No.: 122079-94-1
• Molecular Formula: C₃₆H₅₀O₉
• Molecular Weight: 626.788
• Mol file: 122079-94-1.mol

Synonyms:8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid

Chemical Property of 8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid

There total 1 articles about 8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

8-ethoxycarbonyloctyl-6-O-acetyl-4-O-allyl-2,3-di-O-benzyl-α,β-D-glucopyranosid (122079-93-0,122080-11-9) → 8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-β-D-glucopyranosid (122079-95-2) + 8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid (122079-94-1)

Guidance literature:

With hydrogen; (1,5-cyclooctadiene)[bis(methyldiphenylphosphine)]iridium(I) hexafluorophosphate; In various solvent(s); for 4h; Ambient temperature;

DOI:10.1016/0008-6215(89)84034-0

Reference yield: 88.0%

8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid (122079-94-1) → 8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranoside (122079-96-3)

Guidance literature:

With mercury dichloride; mercury(II) oxide; In water; acetone; for 1h; Ambient temperature;

DOI:10.1016/0008-6215(89)84034-0

Reference yield:

8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-4-O-(1-propenyl)-α-D-glucopyranosid (122079-94-1) → 8-ethoxycarbonyloctyl-4,6-di-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranosid (122079-97-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 88 percent / HgO, HgCl₂ / acetone; H₂O / 1 h / Ambient temperature

2: 98 percent / pyridine / 3 h / Ambient temperature

With pyridine; mercury dichloride; mercury(II) oxide; In water; acetone;

DOI:10.1016/0008-6215(89)84034-0

upstream raw materials:

8-ethoxycarbonyloctyl-6-O-acetyl-4-O-allyl-2,3-di-O-benzyl-α,β-D-glucopyranosid

Downstream raw materials:

8-ethoxycarbonyloctyl-6-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranoside

8-ethoxycarbonyloctyl-4,6-di-O-acetyl-2,3-di-O-benzyl-α-D-glucopyranosid