N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide

Base Information

Chemical Name:N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide
CAS No.:403830-46-6
Molecular Formula:C₅₀H₃₇BrN₆O₄Zn
Molecular Weight:931.176
Hs Code.:

Synonyms:N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide

Suppliers and Price of N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide

There total 1 articles about N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 128-08-5
N-Bromosuccinimide

: 403830-45-5
N-[5-(10,20-diphenylporphirinato) zinc(II)]-N'-(octyl)pyromellitic diimide

: 403830-46-6
N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide

Guidance literature:: In dichloromethane; ligand in CH2Cl2 was added to soln. of Zn-complex in CH2Cl2 under N2, stirred at room temp. for 5 min, quenched with acetone; washed with water, dried over Na2SO4, volatiles were removed, chromd. onsilica gel with CHCl3;
DOI:10.1021/ic0108641

Reference yield: 89.0%

: 403830-46-6
N-[5-(15-bromo-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide

: 7646-85-7,24359-56-6
zinc(II) chloride

: 1066-54-2
trimethylsilylacetylene

: N-[5-(15-(2-(triisopropylsilyl)ethynyl)-10,20-diphenylporphinato)zinc(II)]-N'-(octyl)pyromellitic diimide

Guidance literature:: With n-butyllithium; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; soln. of ligand in THF was cooled to -78°C under N2, n-BuLi in hexane was added with stirring, warmed to room temp., ZnCl2 was added, stirred for 10 min, Zn-complex and Pd(PPh3)4 were added in THF, stirred for4 h under N2; TLC with CHCl3, diluted with ethyl acetate, washed with water, dried over CaCl2, evapd., column chromy. with CHCl3;
DOI:10.1021/ic0108641