Cyclopropanecarboxylic acid, 1-amino-2,2-dimethyl-, methyl ester, (1S)- (9CI)

Base Information

Chemical Name:Cyclopropanecarboxylic acid, 1-amino-2,2-dimethyl-, methyl ester, (1S)- (9CI)
CAS No.:758684-39-8
Molecular Formula:C₇H₁₃NO₂
Molecular Weight:143.186
Hs Code.:
Mol file:758684-39-8.mol

Synonyms:Cyclopropanecarboxylic acid, 1-amino-2,2-dimethyl-, methyl ester, (1S)- (9CI)

Suppliers and Price of Cyclopropanecarboxylic acid, 1-amino-2,2-dimethyl-, methyl ester, (1S)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 2 raw suppliers

Chemical Property of Cyclopropanecarboxylic acid, 1-amino-2,2-dimethyl-, methyl ester, (1S)- (9CI)

Chemical Property:

PSA：52.32000
LogP:0.98710

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Cyclopropanecarboxylic acid, 1-amino-2,2-dimethyl-, methyl ester, (1S)- (9CI)

There total 6 articles about Cyclopropanecarboxylic acid, 1-amino-2,2-dimethyl-, methyl ester, (1S)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 132785-25-2
(S)-4-bromo-N-phthaloylleucine methyl ester

: 758684-39-8
(S)-1-Amino-2,2-dimethyl-cyclopropanecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) NaBH₄, 2.) SOCl₂ / 1.) -10 deg C, 15 min, 2.) r.t., 16 h

2: 63 percent / MeONa / methanol / 30 h / Ambient temperature

3: 96 percent / sodium bromate, ceric ammonium nitrate, H₂O / acetonitrile / 16 h / 80 °C

4: NaBH₄, H₂O / propan-2-ol / 16 h / Ambient temperature

With sodium bromate; sodium tetrahydroborate; thionyl chloride; ammonium cerium(IV) nitrate; water; sodium methylate; In methanol; isopropyl alcohol; acetonitrile;

Reference yield:

: 220000-13-5
(S)-N-Phthaloyl-2,3-methanovaline methyl ester

: 758684-39-8
(S)-1-Amino-2,2-dimethyl-cyclopropanecarboxylic acid methyl ester

Guidance literature:: With sodium tetrahydroborate; water; In isopropyl alcohol; for 16h; Ambient temperature;

Reference yield:

: 220000-18-0
(S)-1-((R)-1-Methoxy-3-oxo-1,3-dihydro-isoindol-2-yl)-2,2-dimethyl-cyclopropanecarboxylic acid methyl ester

: 758684-39-8
(S)-1-Amino-2,2-dimethyl-cyclopropanecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / sodium bromate, ceric ammonium nitrate, H₂O / acetonitrile / 16 h / 80 °C

2: NaBH₄, H₂O / propan-2-ol / 16 h / Ambient temperature

With sodium bromate; sodium tetrahydroborate; ammonium cerium(IV) nitrate; water; In isopropyl alcohol; acetonitrile;