(E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene)

Base Information

• Chemical Name: (E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene)
• CAS No.: 200072-39-5
• Molecular Formula: C₁₅H₄F₁₀
• Molecular Weight: 374.181
• Mol file: 200072-39-5.mol

Synonyms:(E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene)

Chemical Property of (E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene)

There total 5 articles about (E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

Pentafluorobenzene (363-72-4) + 1-allyl-2,3,4,5,6-pentafluorobenzene (1736-60-3) → (E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene) (200072-39-5)

Guidance literature:

With oxygen; palladium diacetate; silver(l) oxide; Trimethylacetic acid; In dimethyl sulfoxide; N,N-dimethyl-formamide; at 120 ℃; for 24h; under 760.051 Torr; regioselective reaction; Mechanism; Sealed tube;

DOI:10.1039/c4cc02023e

Reference yield:

1,2,3,4,5-pentafluoro-6-iodobenzene (827-15-6) → (E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene) (200072-39-5)

Guidance literature:

Multi-step reaction with 2 steps

1: Triphenylphosphine oxide / hexane; tetrahydrofuran / 1 h / 0 °C / Schlenk technique; Inert atmosphere

2: Triphenylphosphine oxide / hexane; tetrahydrofuran / 16 h / 0 - 50 °C / Schlenk technique; Inert atmosphere

With Triphenylphosphine oxide; In tetrahydrofuran; hexane;

DOI:10.1016/j.tet.2015.05.107

Reference yield:

(E)-3-(perfluorophenyl)prop-2-en-1-ol → (E)-6,6'-(prop-1-ene-1,3-diyl)bis(1,2,3,4,5-pentafluorobenzene) (200072-39-5)

Guidance literature:

Multi-step reaction with 2 steps

1: phosphorus tribromide / diethyl ether / 1 h / 0 °C / Inert atmosphere

2: Triphenylphosphine oxide / hexane; tetrahydrofuran / 16 h / 0 - 50 °C / Schlenk technique; Inert atmosphere

With phosphorus tribromide; Triphenylphosphine oxide; In tetrahydrofuran; diethyl ether; hexane;

DOI:10.1016/j.tet.2015.05.107

upstream raw materials:

Pentafluorobenzene

1-allyl-2,3,4,5,6-pentafluorobenzene

1,2,3,4,5-pentafluoro-6-iodobenzene

ethyl (E)-3-pentafluorophenylacrylate