(7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride

Base Information

• Chemical Name: (7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride
• CAS No.: 1616954-85-8
• Molecular Formula: C₃₇H₄₀ClCuN₂
• Molecular Weight: 611.737
• Mol file: 1616954-85-8.mol

Synonyms:(7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride

Chemical Property of (7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride

There total 4 articles about (7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium chloride (1246183-55-0) + copper(l) chloride → (7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride (1616954-85-8)

Guidance literature:

With potassium carbonate; In acetone; at 60 ℃; for 24h;

DOI:10.1016/j.poly.2021.115033

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) → (7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride (1616954-85-8)

Guidance literature:

Multi-step reaction with 3 steps

1: acetic acid / acetonitrile / 5 h / Reflux; Inert atmosphere; Schlenk technique

2: 16 h / 100 °C / Inert atmosphere; Schlenk technique

3: sodium t-butanolate / tetrahydrofuran / Inert atmosphere; Schlenk technique

With acetic acid; sodium t-butanolate; In tetrahydrofuran; acetonitrile;

DOI:10.1080/00958972.2021.1871901

Reference yield:

acenaphthene quinone (82-86-0) → (7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium)copper(I) chloride (1616954-85-8)

Guidance literature:

Multi-step reaction with 3 steps

1: acetic acid / acetonitrile / 5 h / Reflux; Inert atmosphere; Schlenk technique

2: 16 h / 100 °C / Inert atmosphere; Schlenk technique

3: sodium t-butanolate / tetrahydrofuran / Inert atmosphere; Schlenk technique

With acetic acid; sodium t-butanolate; In tetrahydrofuran; acetonitrile;

DOI:10.1080/00958972.2021.1871901

upstream raw materials:

7,9-bis(2,6-diisopropylphenyl)-7H-acenaphtho[1,2-d]imidazol-9-ium chloride

2,6-diisopropylbenzenamine

acenaphthene quinone