(4-Chloro-phenyl)-phenyl-methaneselone

Base Information

• Chemical Name: (4-Chloro-phenyl)-phenyl-methaneselone
• CAS No.: 160425-07-0
• Molecular Formula: C₁₃H₉ClSe
• Molecular Weight: 279.627
• Mol file: 160425-07-0.mol

Synonyms:(4-Chloro-phenyl)-phenyl-methaneselone

Chemical Property of (4-Chloro-phenyl)-phenyl-methaneselone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-Chloro-phenyl)-phenyl-methaneselone

There total 4 articles about (4-Chloro-phenyl)-phenyl-methaneselone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

<(4-chlorophenyl)phenylmethylene>triphenylphosphorane (153785-60-5) → Triphenylphosphine selenide (3878-44-2) + (4-Chloro-phenyl)-phenyl-methaneselone (160425-07-0)

Guidance literature:

With selenium; In toluene; at 80 ℃; for 8h;

Reference yield:

<(4-chlorophenyl)phenylmethylene>triphenylphosphorane (153785-60-5) → (4-Chloro-phenyl)-phenyl-methaneselone (160425-07-0)

Guidance literature:

With selenium; In toluene; at 75 ℃;

DOI:10.1021/ja00149a015

Reference yield:

1-chloro-4-(chloro(phenyl)methyl)benzene (134-83-8,60035-71-4) → (4-Chloro-phenyl)-phenyl-methaneselone (160425-07-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 88 percent / 6 h / 160 °C

2: 67 percent / NaNH₂ / toluene; tetrahydrofuran / Ambient temperature

3: Se / toluene / 8 h / 80 °C

With selenium; sodium amide; In tetrahydrofuran; toluene;

upstream raw materials:

<(4-chlorophenyl)phenylmethylene>triphenylphosphorane

1-chloro-4-(chloro(phenyl)methyl)benzene

<(4-chlorophenyl)phenylmethyl>triphenylphosphonium chloride

Downstream raw materials:

1r,2c-bis-(4-chloro-phenyl)-1,2t-diphenyl-ethene