6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine)

Base Information

Chemical Name:6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine)
CAS No.:1237736-76-3
Molecular Formula:C₂₂H₂₇N₅
Molecular Weight:361.49
Hs Code.:

Synonyms:6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine)

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Chemical Property of 6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine)

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Technology Process of 6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine)

There total 6 articles about 6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1237736-74-1
6,6'-(2,2'-(5-(2,5-dimethyl-1H-pyrrol-1-yl)-1,3-phenylene)bis(ethane-2,1-diyl))bis(2-(2,5-dimethyl-1H-pyrrol-1-yl)-4-methylpyridine)

: 1237736-76-3
6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine)

Guidance literature:: With hydroxylamine hydrochloride; water; In ethanol; at 100 ℃; for 20h; Inert atmosphere;
DOI:10.1021/jm101071n

Reference yield: 85.0%

: 1237736-76-3
6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine)

Guidance literature:

Reference yield:

: 307341-12-4
dimethyl 5-(2,5-dimethyl-1H-pyrrol-1-yl)isophthalate

: 1237736-76-3
6,6'-(2,2'-(5-amino-1,3-phenylene)bis(ethane-2,1-diyl))bis(4-methylpyridin-2-amine)

Guidance literature:: Multi-step reaction with 4 steps

1.1: diisobutylaluminium hydride / tetrahydrofuran; toluene / -78 - 20 °C / Inert atmosphere

2.1: carbon tetrabromide; triphenylphosphine / dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C / Inert atmosphere

3.2: 0 °C / Inert atmosphere

4.1: hydroxylamine hydrochloride; water / ethanol / 20 h / 100 °C / Inert atmosphere

With n-butyllithium; carbon tetrabromide; hydroxylamine hydrochloride; water; diisobutylaluminium hydride; triphenylphosphine; In tetrahydrofuran; ethanol; hexane; dichloromethane; toluene;
DOI:10.1021/jm101071n