((2,6-ⁱPr₂C₆H₃)NCH₂CH₂N(2,6-ⁱPr₂C₆H₃))Y(CH₂SiMe₃)(THF)₂

Base Information

• Chemical Name: ((2,6-ⁱPr₂C₆H₃)NCH₂CH₂N(2,6-ⁱPr₂C₆H₃))Y(CH₂SiMe₃)(THF)₂
• CAS No.: 708268-52-4
• Molecular Formula: C₃₈H₆₅N₂O₂SiY
• Molecular Weight: 698.938
• Mol file: 708268-52-4.mol

Synonyms:((2,6-ⁱPr₂C₆H₃)NCH₂CH₂N(2,6-ⁱPr₂C₆H₃))Y(CH₂SiMe₃)(THF)₂

Chemical Property of ((2,6-ⁱPr₂C₆H₃)NCH₂CH₂N(2,6-ⁱPr₂C₆H₃))Y(CH₂SiMe₃)(THF)₂

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of ((2,6-ⁱPr₂C₆H₃)NCH₂CH₂N(2,6-ⁱPr₂C₆H₃))Y(CH₂SiMe₃)(THF)₂

There total 2 articles about ((2,6-ⁱPr₂C₆H₃)NCH₂CH₂N(2,6-ⁱPr₂C₆H₃))Y(CH₂SiMe₃)(THF)₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

bis(tetrahydrofuran)tris(trimethylsilylmethyl)yttrium(III) + N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diamine (134030-22-1) → ((2,6-iPr2C6H3)NCH2CH2N(2,6-iPr2C6H3))Y(CH2SiMe3)(THF)2 (708268-52-4)

Guidance literature:

In toluene; under Ar; soln. of Y complex in toluene added dropwise to soln. of ligand in toluene at -25°C; stirred at room temp. for 14 h; filtered; volatiles removed from filtrate under vac.; dissolved with hexane; recrystd. from hexane at -35°C; elem. anal.;

DOI:10.1021/om700988n

Reference yield:

[(Y((C6H3-2,6-(isopropyl)2)N(CH2)2N(C6H3-2,6-(isopropyl)2))I(THF)2)2] + trimethylsilylmethyl potassium → ((2,6-iPr2C6H3)NCH2CH2N(2,6-iPr2C6H3))Y(CH2SiMe3)(THF)2 (708268-52-4)

Guidance literature:

In benzene; (N2 or Ar); using Schlenk techniques; treatment of Y(C6H3(CH(CH3)2)2N(CH2)2NC6H3(CH(CH3)2)2)I(THF)2 with KCH2SiMe3 in benzene; not isolated; monitoring by NMR;

DOI:10.1039/b400149d

Reference yield: 100.0%

7,8-benzoquinoline (230-27-3) + ((2,6-iPr2C6H3)NCH2CH2N(2,6-iPr2C6H3))Y(CH2SiMe3)(THF)2 (708268-52-4) → C47H62N3O2Y

Guidance literature:

In benzene; at 20 ℃; for 120h;

DOI:10.1039/c5sc01599e

upstream raw materials:

N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diamine