1,3,5-tris(4'-carboxyphenylsulphonyl)benzene

Base Information

Chemical Name:1,3,5-tris(4'-carboxyphenylsulphonyl)benzene
CAS No.:111851-62-8
Molecular Formula:C₂₇H₁₈O₁₂S₃
Molecular Weight:630.631
Hs Code.:

Synonyms:1,3,5-tris(4'-carboxyphenylsulphonyl)benzene

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Chemical Property of 1,3,5-tris(4'-carboxyphenylsulphonyl)benzene

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Technology Process of 1,3,5-tris(4'-carboxyphenylsulphonyl)benzene

There total 2 articles about 1,3,5-tris(4'-carboxyphenylsulphonyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 6618-53-7
1,3,5-tris(tosyl)benzene

: 111851-62-8
1,3,5-tris(4'-carboxyphenylsulphonyl)benzene

Guidance literature:: With nitric acid; In water; at 220 ℃; for 12h; Autoclave;
DOI:10.1021/ic2007292

Reference yield:

: 3185-99-7
Methyl p-tolyl sulfone

: 111851-62-8
1,3,5-tris(4'-carboxyphenylsulphonyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1: orthoformic acid ethyl ester / 130 °C

2: CrO₃; acetic acid; acetic acid anhydride / 30 °C / weiteres Reagens: H₂SO₄

With chromium(VI) oxide; acetic anhydride; acetic acid; orthoformic acid triethyl ester;
DOI:10.1021/ja01519a068

Reference yield: 70.0%

: 553-26-4
4,4'-bipyridine

: cobalt(II) nitrate hexahydrate

: 111851-62-8
1,3,5-tris(4'-carboxyphenylsulphonyl)benzene

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 3Co⁽²⁺⁾*4H₂O*2C₆H₃(SO₂C₆H₄COO)3^(3-)*(C₅H₄N)2*4.5HCON(CH₃)2=Co₃(H₂O)4(C₂₇H₁₅O₁₂S₃)2(C₅H₄N)2(HCON(CH₃)2)2*2.5HCON(CH₃)2

Guidance literature:: In water; N,N-dimethyl-formamide; High Pressure; heating a mixt. of Co salt, ligand, 4,4'-bpy in DMF/water (4:1 vol.) at 100°C for 50 h, slow cooling to room temp. over 12 h; elem. anal.;
DOI:10.1021/ic2007292