[ReH(CO)(NO)(P(C₆H₅)3)3]⁽¹⁺⁾*ClO₄^(1-)=[ReH(CO)(NO)(P(C₆H₅)3)3]ClO₄

Base Information

• Chemical Name: [ReH(CO)(NO)(P(C₆H₅)3)3]⁽¹⁺⁾*ClO₄^(1-)=[ReH(CO)(NO)(P(C₆H₅)3)3]ClO₄
• CAS No.: 98481-38-0
• Molecular Formula: C₅₅H₄₆NO₂P₃Re*ClO₄
• Molecular Weight: 1131.55
• Mol file: 98481-38-0.mol

Synonyms:[ReH(CO)(NO)(P(C₆H₅)3)3]⁽¹⁺⁾*ClO₄^(1-)=[ReH(CO)(NO)(P(C₆H₅)3)3]ClO₄

Chemical Property of [ReH(CO)(NO)(P(C₆H₅)3)3]⁽¹⁺⁾*ClO₄^(1-)=[ReH(CO)(NO)(P(C₆H₅)3)3]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of [ReH(CO)(NO)(P(C₆H₅)3)3]⁽¹⁺⁾*ClO₄^(1-)=[ReH(CO)(NO)(P(C₆H₅)3)3]ClO₄

There total 1 articles about [ReH(CO)(NO)(P(C₆H₅)3)3]⁽¹⁺⁾*ClO₄^(1-)=[ReH(CO)(NO)(P(C₆H₅)3)3]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

[ReH2(nitrosyl)(triphenylphosphine)3] (58694-74-9) → [ReH(CO)(NO)(P(C6H5)3)3](1+)*ClO4(1-)=[ReH(CO)(NO)(P(C6H5)3)3]ClO4 (98481-38-0)

Guidance literature:

With sodium ethoxide; CO; HClO₄; In ethanol; dichloromethane; passing CO through a suspension of 0.50 mmol dihydride in CH2Cl2-C2H5OH(1:1) for 15 min; addn. of 70% perchloric acid; dropwise addn. of 0.5 MNaOC2H5 soln. (slightly acidic); passing CO through soln. for 15 min; reducing solvent in vacuum; N2 atm.;; crystn. from the sealed and undisturbed soln. within 24-48 h; recrystallization from CH2Cl2-ethanol containing 1 drop of perchloric acid; elem.anal.;;

upstream raw materials:

[ReH₂(nitrosyl)(triphenylphosphine)3]

Refernces