BIS(TETRAETHYLAMMONIUM) BIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)ZINCATE

Base Information

• Chemical Name: BIS(TETRAETHYLAMMONIUM) BIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)ZINCATE
• CAS No.: 72022-68-5
• Molecular Formula: C22H40N2S10Zn
• Molecular Weight: 718.623
• Mol file: 72022-68-5.mol

Synonyms:BIS(TETRAETHYLAMMONIUM) BIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)ZINCATE;BIS(TETRAETHYLAMMONIUM)BIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)ZINCATE (II);BIS(TETRAETHYLAMMONIUM)BIS(THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)ZINCATE(II);BIS(TETRAETHYLAMM.)BIS(2-THIOXO-DITHIOLE -4,5-DITHIOLATO)ZI;Bis(4,5-dimercapto-1,3-dithiole-2-thionato)zincate(II) bis(tetraethylammonium) salt

Chemical Property of BIS(TETRAETHYLAMMONIUM) BIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)ZINCATE

Chemical Property:

• Melting Point: 201-206 °C
• PSA: 278.34000
• LogP: 11.06690
• Sensitive.: Light Sensitive

Purity/Quality:

99% ^*data from raw suppliers

Bis(tetraethylammonium)-bis-(2-thioxo-1,3-dithiole-4,5-dithiolato)zincate(II) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(TETRAETHYLAMMONIUM) BIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)ZINCATE

There total 5 articles about BIS(TETRAETHYLAMMONIUM) BIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)ZINCATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

carbon disulfide (75-15-0,12122-00-8) + zinc(II) chloride (7646-85-7,24359-56-6) → bis(tetraethylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolate)zincate (72022-68-5)

Guidance literature:

carbon disulfide; zinc(II) chloride; With sodium; In methanol; water;

With tetraethylammonium bromide; In methanol; water;

DOI:10.1039/c3dt51464a

Reference yield: 84.0%

carbon disulfide (75-15-0,12122-00-8) + tetraethylammonium bromide (71-91-0) + zinc(II) chloride (7646-85-7,24359-56-6) → bis(tetraethylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolate)zincate (72022-68-5)

Guidance literature:

carbon disulfide; With sodium; In N,N-dimethyl-formamide; at 25 ℃; Cooling with ice;

tetraethylammonium bromide; zinc(II) chloride; With ammonium hydroxide; In methanol; water; N,N-dimethyl-formamide; for 10.75h; Cooling with ice;

DOI:10.1021/acs.orglett.6b03539

Reference yield:

tetraethylammonium bromide (71-91-0) + disodium 1,3-dithiol-2-thione-4,5-dithiolate (54995-24-3) + zinc(II) chloride (7646-85-7,24359-56-6) → bis(tetraethylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolate)zincate (72022-68-5)

Guidance literature:

With ammonium hydroxide; In methanol; water; Cooling with ice;

upstream raw materials:

carbon disulfide

tetraethylammonium iodide

zinc(II) sulfate

tetraethylammonium bromide

Downstream raw materials:

Au₄(C₃S₅)2(CH₂(P(C₆H₅)2)2)2*CH₃COCH₃

4,5-bis(3,5-di-tert-butylbenzylthio)-1,3-dithiole-2-thione

4,5-bis(2-cyanoethylthio)-1,3-dithiol-2-one

4,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethylsulfanyl]-1,3-dithiole-2-thione