PhSiMe₂C(n-C₆H₁₃)CHB(pinacolato)

Base Information

• Chemical Name: PhSiMe₂C(n-C₆H₁₃)CHB(pinacolato)
• CAS No.: 185989-92-8
• Molecular Formula: C₂₂H₃₇BO₂Si
• Molecular Weight: 372.431
• Mol file: 185989-92-8.mol

Synonyms:PhSiMe₂C(n-C₆H₁₃)CHB(pinacolato)

Chemical Property of PhSiMe₂C(n-C₆H₁₃)CHB(pinacolato)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of PhSiMe₂C(n-C₆H₁₃)CHB(pinacolato)

There total 9 articles about PhSiMe₂C(n-C₆H₁₃)CHB(pinacolato) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

n-octyne (629-05-0) + dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane (185990-03-8) → (Z)-dimethyl(phenyl)(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oct-1-en-1-yl)silane (185989-92-8)

Guidance literature:

tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triethyl phosphite; In toluene; at 110 ℃; for 4h;

DOI:10.1016/S0040-4020(99)00444-5

Reference yield: 88.0%

n-octyne (629-05-0) + dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane (185990-03-8) → PhSiMe2C(n-C6H13)CHB(pinacolato) (185989-92-8)

Guidance literature:

With Pd(1,3,4,5-tetramethylimidazol-2-ylidene)₂(diphenylacetylene); In benzene-d6; at 20 ℃; for 0.5h; stereoselective reaction;

DOI:10.1021/acscatal.6b00127

Reference yield: 85.0%

n-octyne (629-05-0) + isopropyl alcohol (67-63-0,8013-70-5) + dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane (185990-03-8) → (Z)-dimethyl(phenyl)(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)oct-1-en-1-yl)silane (185989-92-8)

Guidance literature:

n-octyne; dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane; With (η³-C3H5)Pd(PPh3)Cl; In toluene; at 20 ℃; for 96h; Inert atmosphere;

isopropyl alcohol; With pyridine; In toluene; at 20 ℃; for 1h; regioselective reaction; Inert atmosphere;

DOI:10.1021/ja105096r

upstream raw materials:

n-octyne

dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

2,3-dimethyl-2,3-butane diol

(bis(diethylamino)-boranyl)dimethylphenylsilane