4-trifluoromethylcinnamyl methyl carbonate

Base Information

Chemical Name:4-trifluoromethylcinnamyl methyl carbonate
CAS No.:776296-21-0
Molecular Formula:C₁₂H₁₁F₃O₃
Molecular Weight:260.213
Hs Code.:

Synonyms:4-trifluoromethylcinnamyl methyl carbonate

Suppliers and Price of 4-trifluoromethylcinnamyl methyl carbonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-trifluoromethylcinnamyl methyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-trifluoromethylcinnamyl methyl carbonate

There total 1 articles about 4-trifluoromethylcinnamyl methyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 180635-56-7
p-(trifluoromethyl)cinnamyl alcohol

: 79-22-1
methyl chloroformate

: 776296-21-0
4-trifluoromethylcinnamyl methyl carbonate

Guidance literature:: p-(trifluoromethyl)cinnamyl alcohol; With pyridine; In dichloromethane; at 0 ℃; for 0.25h; Inert atmosphere;

methyl chloroformate; In dichloromethane; at 0 - 20 ℃; for 12h; Inert atmosphere;
DOI:10.1021/acs.orglett.0c03806

Reference yield: 99.0%

: 776296-21-0
4-trifluoromethylcinnamyl methyl carbonate

: 3524-62-7
benzoin monomethyl ether

: (2R,3R)-2-methoxy-1,2-diphenyl-3-(4-(trifluoromethyl)phenyl)pent-4-en-1-one

: 2-methoxy-1,2-diphenyl-3-(4-(trifluoromethyl)phenyl)pent-4-en-1-one

Guidance literature:: benzoin monomethyl ether; With copper(I) bromide; lithium hexamethyldisilazane; In tetrahydrofuran; at 20 ℃; for 0.583333h; Inert atmosphere;

4-trifluoromethylcinnamyl methyl carbonate; With C₆₁H₅₄IrNO₂P⁽¹⁺⁾*BF₄^(1-); In tetrahydrofuran; at 5 ℃; for 12h; stereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201600235

Reference yield: 94.0%

: 776296-21-0
4-trifluoromethylcinnamyl methyl carbonate

: methyl 2-fluoro-2-(pyridin-2-yl)acetate

: methyl (2R,3R)-2-fluoro-2-(pyridin-2-yl)-3-(4-(trifluoromethyl)phenyl)pent-4-enoate

Guidance literature:: With tetrakis(actonitrile)copper(I) hexafluorophosphate; (C₈H₁₂)Ir(C₃H₄C₆H₅)(CH₂CHC₆H₅N(CHC₆H₅CH₃)PO₂C₂₀H₁₂)⁽¹⁺⁾*BF₄^(1-)=((C₈H₁₂)Ir(C₃H₄C₆H₅)(CH₂CHC₆H₅N(CHC₆H₅CH₃)PO₂C₂₀H₁₂))BF₄; caesium carbonate; (R,R)-1,2-bis(2,5-diphenylphospholanyl)ethane; In tetrahydrofuran; at 20 ℃; for 12h; stereoselective reaction; Inert atmosphere; Sealed tube;
DOI:10.1021/jacs.9b04440