(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)

Base Information

Chemical Name:(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)
CAS No.:221243-92-1
Molecular Formula:C₄₃H₄₃FeNP₂
Molecular Weight:691.616
Hs Code.:

Synonyms:(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)

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Chemical Property of (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)

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Technology Process of (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)

There total 2 articles about (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 626-55-1,163928-56-1
3-Bromopyridine

: (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.CH

: 221243-92-1
(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)

Guidance literature:: With catalyst: PdCl₂(PPh₃)2/CuI; In further solvent(s); Ar-atmosphere; refluxing in HN(i-Pr)2 for 12 h; distn. off of solvent (low temp.), extn. into PhMe, filtration (Celite),evapn., washing (pentane, -40°C; then MeCN, -20°C), dryin g (vac.); can be recrystallized (PhMe/pentane); elem. anal.;
DOI:10.1016/s0020-1693(99)00135-8

Reference yield: 68.0%

: 1046457-98-0
[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)Fe(5,2-C5H3NBr)]

: 5,5'-[(η2-1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)FeCC]2-[2,2'-(C5H3N)2]

: 221243-92-1
(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)

Guidance literature:: With Pd(OAc)2; K₂CO₃; In N,N-dimethyl-formamide; isopropyl alcohol; (Ar); Fe complex, K2CO3 and Pd salt were introduced in DMF in Schlenk tube; i-PrOH was added; heated with stirring at 110°C for 16 h; cooled to room temp.; evapd. (vac.); extd. (toluene); evapd.; washed (Et2O, pentane); dissolved in THF; filtered (silica, THF/toluene, 1/1); evapd.;
DOI:10.1021/om800388j

Reference yield: 87.0%

: ferrocenium hexafluorophosphate

: 221243-92-1
(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)

: 221244-18-4
[(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-m-(C5H4N)][PF6]

Guidance literature:: In dichloromethane; 0.9 equiv. (Cp2Fe)PF6, stirring at room temp. for 1 h; concn. (vac.), pptn. on pentane addn., decantation, washing (PhMe, Et2O), drying (vac.); elem. anal.;
DOI:10.1016/s0020-1693(99)00135-8