5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid

Base Information

• Chemical Name: 5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid
• CAS No.: 350024-36-1
• Molecular Formula: C₃₀H₁₄N₂O₁₂
• Molecular Weight: 594.447
• Mol file: 350024-36-1.mol

Synonyms:5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid

Chemical Property of 5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid

Chemical Property:

• Boiling Point: 1102.3±65.0 °C(Predicted)
• Density: 1.810±0.06 g/cm3(Predicted)

Purity/Quality:

97% ^*data from raw suppliers

1,3-Benzenedicarboxylicacid,5,5'-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis- 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid

There total 1 articles about 5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,4,5,8-naphthalenetetracarboxylic dianhydride (81-30-1) + 5-aminoisophthalic acid (99-31-0) → 5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid (350024-36-1)

Guidance literature:

at 180 ℃; for 1h;

DOI:10.1039/c0ce00542h

Reference yield: 77.0%

5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid (350024-36-1) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → C30H10N2O12(4-)*2Ca(2+)*4C3H7NO

Guidance literature:

With calcium(II) nitrate tetrahydrate; at 100 ℃; for 72h; Sealed tube;

DOI:10.1039/c2cc37497h

Reference yield: 76.0%

cerium(III) nitrate hexahydrate + 5,5′-(1,3,6,8-tetrahydro-1,3,6,8-tetraoxobenzo[lmn][3,8]phenanthroline-2,7-diyl)bis-1,3-benzenedicarboxylic acid (350024-36-1) + tetrabutylammonium hexatungstate + N,N-dimethyl-formamide (68-12-2,33513-42-7) → C30H10N2O12(4-)*2Ce(3+)*8C3H7NO*W6O19(2-)

Guidance literature:

In acetonitrile; at 90 ℃; for 48h;

DOI:10.1016/j.molstruc.2021.132011

upstream raw materials:

1,4,5,8-naphthalenetetracarboxylic dianhydride

5-aminoisophthalic acid