<1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane

Base Information

Chemical Name:<1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane
CAS No.:110366-52-4
Molecular Formula:C₂₅H₂₇F₃O₅S
Molecular Weight:496.548
Hs Code.:

Synonyms:<1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane

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Chemical Property of <1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane

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Technology Process of <1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane

There total 3 articles about <1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 20445-33-4,39637-99-5
(R)-methoxytrifluoromethylphenylacetyl chloride

: 110416-52-9
(E)-<1(S),3(S)>-3-<3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentanol

: 110366-52-4
<1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane

Guidance literature:: With dmap; triethylamine; In toluene; for 12h; Ambient temperature;
DOI:10.1021/jo00381a002

Reference yield:

: 110366-40-0
(E)-<3(S),S(R)>-3-<3-(p-tolylsulfinyl)-2-propen-1-yl>cyclopentanone

: 110366-52-4
<1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane

Guidance literature:: Multi-step reaction with 3 steps

1: 0.06 g / NaBH₄ / methanol / 0.5 h / -20 °C

2: 89 percent / m-chloroperoxybenzoic acid (MCPBA) / CH₂Cl₂ / 5 h / 0 °C

3: 90 percent / 4-(dimethylamino)pyridine (DMAP), triethylamine / toluene / 12 h / Ambient temperature

With dmap; sodium tetrahydroborate; triethylamine; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; toluene;
DOI:10.1021/jo00381a002

Reference yield:

: 110366-51-3
(E)-<3(S),S(R)>-3-<3-(p-tolylsulfinyl)-2-propen-1-yl>cyclopentanol

: 110366-52-4
<1(S),3(S),1'(R)>-1-<α-methoxy-α-(trifluoromethyl)phenylacetoxy>-3-<(E)-3-(p-tolylsulfonyl)-2-propen-1-yl>cyclopentane

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / m-chloroperoxybenzoic acid (MCPBA) / CH₂Cl₂ / 5 h / 0 °C

2: 90 percent / 4-(dimethylamino)pyridine (DMAP), triethylamine / toluene / 12 h / Ambient temperature

With dmap; triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; toluene;
DOI:10.1021/jo00381a002