C₄₇H₅₄BrNO₉Si

Base Information

Chemical Name:C₄₇H₅₄BrNO₉Si
CAS No.:928657-79-8
Molecular Formula:C₄₇H₅₄BrNO₉Si
Molecular Weight:884.937
Hs Code.:

C<sub>47</sub>H<sub>54</sub>BrNO<sub>9</sub>Si

Synonyms:C₄₇H₅₄BrNO₉Si

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Chemical Property of C₄₇H₅₄BrNO₉Si

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Technology Process of C₄₇H₅₄BrNO₉Si

There total 6 articles about C₄₇H₅₄BrNO₉Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-dimethyl 2-[(phenylmethoxy)methyl]cyclopropane-1,1-dicarboxylate

: 928657-78-7
C₂₄H₂₇BrO₃Si

: 51307-59-6
N-(4-methoxybenzyl)hydroxylamine

: 928657-79-8
C₄₇H₅₄BrNO₉Si

Guidance literature:: C₂₄H₂₇BrO₃Si; N-(4-methoxybenzyl)hydroxylamine; With 4 A molecular sieve; ytterbium(III) triflate; In toluene; at 20 ℃; for 3h;

(R)-dimethyl 2-[(phenylmethoxy)methyl]cyclopropane-1,1-dicarboxylate; In toluene; at 100 ℃; for 20h; Further stages.;
DOI:10.1021/ja068047t

Reference yield:

: 928657-74-3
C₈H₆Br₂O₃

: 928657-79-8
C₄₇H₅₄BrNO₉Si

Guidance literature:: Multi-step reaction with 5 steps

1.1: 28.92 g / sodium acetate; p-toluenesulfonhydrazide / tetrahydrofuran; H₂O / 18 h / Heating

2.1: DIBAL / CH₂Cl₂; toluene / 0.5 h / 0 °C

3.1: 41.76 g / imidazole; N,N-dimethylaminopyridine / dimethylformamide / 14 h / 20 °C

4.1: n-BuLi / diethyl ether; hexane / 0.5 h / -78 °C

4.2: 65 percent / diethyl ether; hexane / 0.5 h / Heating

5.1: 4 Angstroem molecular sieves / Yb(OTf)3*xH₂O / toluene / 3 h / 20 °C

5.2: toluene / 20 h / 100 °C

With 1H-imidazole; dmap; n-butyllithium; 4 A molecular sieve; sodium acetate; diisobutylaluminium hydride; toluene-4-sulfonic acid hydrazide; ytterbium(III) triflate; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja068047t

Reference yield:

: 928657-77-6
C₂₃H₂₆Br₂O₂Si

: 928657-79-8
C₄₇H₅₄BrNO₉Si

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / diethyl ether; hexane / 0.5 h / -78 °C

1.2: 65 percent / diethyl ether; hexane / 0.5 h / Heating

2.1: 4 Angstroem molecular sieves / Yb(OTf)3*xH₂O / toluene / 3 h / 20 °C

2.2: toluene / 20 h / 100 °C

With n-butyllithium; 4 A molecular sieve; ytterbium(III) triflate; In diethyl ether; hexane; toluene;
DOI:10.1021/ja068047t