Cyclopentanecarboxylic acid, 3-amino-, (1R,3R)- (9CI)

Base Information

• Chemical Name: Cyclopentanecarboxylic acid, 3-amino-, (1R,3R)- (9CI)
• CAS No.: 71869-43-7
• Molecular Formula: C6H11 N O2
• Molecular Weight: 129.159
• Mol file: 71869-43-7.mol

Synonyms:Cyclopentanecarboxylicacid, 3-amino-, (1R-trans)-; (-)-trans-3-Aminocyclopentanecarboxylic acid

Chemical Property of Cyclopentanecarboxylic acid, 3-amino-, (1R,3R)- (9CI)

Chemical Property:

• Melting Point: 117-120 °C
• Boiling Point: 264.7±33.0 °C(Predicted)
• PKA: 4.44±0.20(Predicted)
• PSA: 63.32000
• Density: 1.190±0.06 g/cm3(Predicted)
• LogP: 0.89870
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

(1R,3R)-3-Amino-cyclopentanecarboxylicacid 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclopentanecarboxylic acid, 3-amino-, (1R,3R)- (9CI)

There total 21 articles about Cyclopentanecarboxylic acid, 3-amino-, (1R,3R)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(1R,3R)-3-((tert-butoxycarbonyl)amino)cyclopentane-1-carboxylic acid (489446-85-7) → (-)-trans-(1R,3R)-3-aminocyclopentane-1-carboxylic acid (71869-43-7)

Guidance literature:

With hydrogenchloride; at 80 ℃; for 5h;

DOI:10.1021/jm050698x

Reference yield: 90.0%

trans-4-aminocyclopent-2-ene-1-carboxylic acid → trans-3-aminocyclopentane-1-carboxylic acid (19042-34-3,19297-28-0,49805-32-5,57376-72-4,71376-02-8,71830-07-4,71830-08-5,71869-43-7,89614-96-0)

Guidance literature:

With hydrogen; 10% palladium on active carbon; In acetic acid; Ambient temperature;

DOI:10.1071/CH9860855

Reference yield: 88.0%

D-pantolactone eser of trans-(1R,3R)-3-phthalimidocyclopentane-1-carboxylic acid → (-)-trans-(1R,3R)-3-aminocyclopentane-1-carboxylic acid (71869-43-7)

Guidance literature:

With hydrogenchloride; acetic acid; for 5h; Heating;

DOI:10.1071/CH9860855

upstream raw materials:

(1R,3R)-3-((tert-butoxycarbonyl)amino)cyclopentane-1-carboxylic acid

D-pantolactone ester of trans-(1S,4S)-4-phthalimidocyclopent-2-ene-1-carboxylic acid

methyl 3-aminocyclopentane-1-carboxylate

3-tosyl-2-azabicyclo [2.2.1]hepta-2,5-diene

Downstream raw materials:

(1R,3R)-3-(9-fluorenylmethoxycarbonylamino)cyclopentanecarboxylic acid

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