N¹,N³,N⁵-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide

Base Information

• Chemical Name: N¹,N³,N⁵-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide
• CAS No.: 725274-03-3
• Molecular Formula: C₂₄H₁₈N₆O₃
• Molecular Weight: 438.445
• Mol file: 725274-03-3.mol

Synonyms:N¹,N³,N⁵-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide

Chemical Property of N¹,N³,N⁵-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

N1,N3,N5-Tri(pyridin-4-yl)benzene-1,3,5-tricarboxamide 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N¹,N³,N⁵-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide

There total 1 articles about N¹,N³,N⁵-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

4-aminopyridine (504-24-5) + 1,3,5-benzene tris(carbonyl chloride) (4422-95-1) → N1,N3,N5-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide (725274-03-3)

Guidance literature:

In N,N-dimethyl-formamide; at 20 ℃;

Reference yield: 99.2%

N1,N3,N5-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide (725274-03-3) → C24H15(2)H3N6O3 (1448849-74-8)

Guidance literature:

N¹,N³,N⁵-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide; With n-butyllithium; water-d2; In dimethyl sulfoxide; at 0 - 70 ℃; for 2h; Inert atmosphere;

With water-d2; for 2h;

DOI:10.1021/ja403002m

Reference yield: 65.0%

N1,N3,N5-tris(pyridin-4-yl)benzene-1,3,5-tricarboxamide (725274-03-3) + water (7732-18-5) + cadmium(II) chloride (10108-64-2) → (N,N',N''-tris(4-pyridyl)trimesic amide)cadmium(II) chloride dihydrate

Guidance literature:

In N,N-dimethyl-formamide; acetonitrile; a MeCN soln. of CdCl2 layered onto a DMF soln. of ligand; crystd. for 2 d; elem. anal.;

DOI:10.1039/b604446h

upstream raw materials:

4-aminopyridine

1,3,5-benzene tris(carbonyl chloride)

Downstream raw materials:

C₂₄H₁₅⁽²⁾H₃N₆O₃

Refernces

• 1、 Hong, Seunghee,Zou, Yang,Moon, Dohyun,Lah, Myoung Soo. "An unprecedented twofold interpenetrating (3,4)-connected 3-D metal-organic framework". . p. 1707 - 1709. Retrieved 2007.
• 2、 Zhao, Xiang,Bu, Xianhui,Zhai, Quan-Guo,Tran, Huy,Feng, Pingyun. "Pore space partition by symmetry-matching regulated ligand insertion and dramatic tuning on carbon dioxide uptake". . p. 1396 - 1399. Retrieved 2015.
• 3、 Wei, Tai-Bao,Qi, Li-Hua,Zhang, Qin-Peng,Zhang, Wen-Huan,Yao, Hong,Zhang, You-Ming,Lin, Qi. "Stimuli-responsive supramolecular polymer network based on bi-pillar[5]arene for efficient adsorption of multiple organic dye contaminants". supporting information. p. 12531 - 12537. Retrieved 2020/09/15.