(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

Base Information

Chemical Name:(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester
CAS No.:247077-99-2
Molecular Formula:C₃₀H₃₅Cl₃N₄O₁₅
Molecular Weight:797.985
Hs Code.:

(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

Synonyms:(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

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Chemical Property of (2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

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Technology Process of (2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

There total 4 articles about (2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 175978-92-4
1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose

: 247077-99-2
(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 66 percent / 4 Angstroem molecular sieves; trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / 4 h / -20 °C

2: benzylamine / diethyl ether / 1 h / 0 °C

3: 148 mg / 4 Angstroem molecular sieves; potassium carbonate / CH₂Cl₂

With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; potassium carbonate; benzylamine; In diethyl ether; dichloromethane; 1: Condensation / 2: Deacetylation / 3: Addition;
DOI:10.1016/S0968-0896(99)00106-6

Reference yield:

: methyl 2,3,4-tri-O-acetyl-α,β-D-glucopyranosyluronate trichloroacetimidate

: 247077-99-2
(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 66 percent / 4 Angstroem molecular sieves; trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / 4 h / -20 °C

2: benzylamine / diethyl ether / 1 h / 0 °C

3: 148 mg / 4 Angstroem molecular sieves; potassium carbonate / CH₂Cl₂

With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; potassium carbonate; benzylamine; In diethyl ether; dichloromethane; 1: Condensation / 2: Deacetylation / 3: Addition;
DOI:10.1016/S0968-0896(99)00106-6

Reference yield:

: 247077-97-0
methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate-(1->4)-1,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-4-O-β-D-glucopyranose

: 247077-99-2
(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-[(2R,3S,4R,5R)-2-acetoxymethyl-5-azido-4-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yloxy]-tetrahydro-pyran-2-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: benzylamine / diethyl ether / 1 h / 0 °C

2: 148 mg / 4 Angstroem molecular sieves; potassium carbonate / CH₂Cl₂

With 4 A molecular sieve; potassium carbonate; benzylamine; In diethyl ether; dichloromethane; 1: Deacetylation / 2: Addition;
DOI:10.1016/S0968-0896(99)00106-6