CIS-TETRACARBONYLBIS(PIPERIDINE)MOLYBDENUM

Base Information

• Chemical Name: CIS-TETRACARBONYLBIS(PIPERIDINE)MOLYBDENUM
• CAS No.: 65337-26-0
• Molecular Formula: C₁₄H₂₂MoN₂O₄
• Molecular Weight: 378.28
• Mol file: 65337-26-0.mol

Synonyms:cis-Bis(piperidine)molybdenumtetracarbonyl; cis-Tetracarbonylbis(piperidine)molybdenum

Chemical Property of CIS-TETRACARBONYLBIS(PIPERIDINE)MOLYBDENUM

Chemical Property:

Purity/Quality:

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

Useful:

Technology Process of CIS-TETRACARBONYLBIS(PIPERIDINE)MOLYBDENUM

There total 2 articles about CIS-TETRACARBONYLBIS(PIPERIDINE)MOLYBDENUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

piperidine (110-89-4) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → cis-tetracarbonylbis(piperidine)molybdenum (59967-36-1,65337-26-0)

Guidance literature:

In methyl cyclohexane; refluxing of soln. of starting materials for 4 h;

Reference yield:

piperidine (110-89-4) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → bis(piperidyl)tetracarbonylmolybdenum(0) (65337-26-0,59967-36-1)

Guidance literature:

In diethylene glycol; Mo complex and ligand refluxed in solvent, under N2;

DOI:10.1039/DT9820002353

Reference yield: 95.0%

cis-tetracarbonylbis(piperidine)molybdenum (59967-36-1,65337-26-0) + 3,4-dimethyl-1-phenylphosphole (30540-36-4) → tetracarbonylbis(1-phenyl-3,4-dimethylphosphole)molybdenum(0) (74391-02-9)

Guidance literature:

In dichloromethane; (Ar); a soln. of Mo-complex and P-compound refluxed for 1 h under stirring; chromy.; elem. anal.;

DOI:10.1021/ja00538a018

upstream raw materials:

piperidine

molybdenum hexacarbonyl

Downstream raw materials:

piperidine

cis-bis(allylphosphine)molybdenum(CO)4

cis-(CHCCH₂PH₂)2molybdenum(CO)4

cis-{molybdenum⁽⁰⁾(carbonyl)4(P(phenyl)3)2}