(2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene

Base Information

Chemical Name:(2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene
CAS No.:140875-15-6
Molecular Formula:C₁₄H₂₁NO₄
Molecular Weight:267.325
Hs Code.:

Synonyms:(2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene

Suppliers and Price of (2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene

There total 2 articles about (2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 102069-84-1
(S)-2-methoxy-1-[[2'-(methoxymethyl)pyrrolidinyl]carbonyl]benzene

: 140875-16-7
((R)-1-Hydroxy-2-methoxy-cyclohexa-2,5-dienyl)-((S)-2-methoxymethyl-pyrrolidin-1-yl)-methanone

: 140875-15-6
(2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene

Guidance literature:: With (-)-(camphorylsulfonyl)oxaziridine; ammonia; potassium; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1) THF, t-butanol, -78 deg C, 2) DME;
DOI:10.1021/jo00036a046

Reference yield:

: 188052-17-7
(2'S)-1-methoxy-6-{[2'-(methoxymethyl)pyrrolidinyl]carbonyl}-1,4-cyclohexadiene

: 140875-16-7
((R)-1-Hydroxy-2-methoxy-cyclohexa-2,5-dienyl)-((S)-2-methoxymethyl-pyrrolidin-1-yl)-methanone

: 140875-15-6
(2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene

Guidance literature:: With (+)-(2S,8aS)-(camphorylsulfonyl)oxaziridine; potassium hydride; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1) THF, RT , 1 h, 2) -78 deg C, 30 min;
DOI:10.1021/jo00036a046

Reference yield: 80.0%

: 140875-15-6
(2'S)-3-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-3-hydroxy-2-methoxy-1,4-cyclohexadiene

: 140875-17-8
(2'S)-1-<<2'-(methoxymethyl)pyrrolidinyl>carbonyl>-1-hydroxy-2-methoxycyclohex-2-ene

Guidance literature:: With hydrogen; (η4-1,5-cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate; In dichloromethane; for 12h; under 760 Torr;
DOI:10.1021/jo00036a046