4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose

Base Information

Chemical Name:4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose
CAS No.:150650-40-1
Molecular Formula:C₂₆H₃₃ClO₇Si
Molecular Weight:521.082
Hs Code.:

Synonyms:4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose

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Chemical Property of 4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose

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Technology Process of 4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose

There total 3 articles about 4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 150673-82-8
3-Chloro-benzoic acid (2R,3S,4S,5R,6S)-5-benzoyloxy-6-bromomethyl-4-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-tetrahydro-pyran-2-yl ester

: 150650-40-1
4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 1h; Yield given; Heating;

Reference yield:

: 121702-70-3
tert-Butyl-dimethyl-((2R,4aR,8S,8aR)-2-phenyl-4,4a,8,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy)-silane

: 150650-40-1
4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) MCPBA, 2.) Ca(OH)2 / 1.) CH₂Cl₂, 0 deg C, 45 min, 2.) CH₂Cl₂, 0 deg C, 20 min

2: NBS, BaCO₃, AIBN / CCl₄ / 0.75 h / Heating

3: n-Bu₃SnH, AIBN / benzene / 1 h / Heating

With calcium hydroxide; N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; 3-chloro-benzenecarboperoxoic acid; barium carbonate; In tetrachloromethane; benzene;

Reference yield:

: 150650-39-8
1-O-(3-chlorobenzoyl)-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4,6-O-(phenylmethylene)-α-D-altropyranose

: 150650-40-1
4-O-benzoyl-1-O-(3-chlorobenzoyl)-6-deoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-α-D-altropyranose

Guidance literature:: Multi-step reaction with 2 steps

1: NBS, BaCO₃, AIBN / CCl₄ / 0.75 h / Heating

2: n-Bu₃SnH, AIBN / benzene / 1 h / Heating

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; barium carbonate; In tetrachloromethane; benzene;