(Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

Base Information

Chemical Name:(Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid
CAS No.:100100-68-3
Molecular Formula:C₁₉H₂₆O₅
Molecular Weight:334.412
Hs Code.:

Synonyms:(Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

Suppliers and Price of (Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

There total 1 articles about (Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 63598-31-2
methyl 4,6-O-(R)-benzylidene-2-deoxy-α-D-erythrohexopyranosid-3-ulose

: 99967-10-9
(n-Butoxymethylen)triphenylphosphoniumchlorid

: 100100-68-3
(Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

: 100100-67-2
(E)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, 30 min, RT 2.) THF; 3 h, -25 deg C; 18 h, RT;
DOI:10.1002/jlac.198619860403

Reference yield: 90.0%

: 100100-68-3
(Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

: 100100-69-4
Methyl-4,6-O-benzyliden-2-desoxy-3-C-formyl-α-D-arabino-hexopyranosid

Guidance literature:: With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In water; acetone; at 40 ℃; for 20h;
DOI:10.1002/jlac.198619860403

Reference yield:

: 100100-68-3
(Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid

: 99967-11-0
Methyl-4,6-O-benzyliden-2-desoxy-3-C-hydroxymethyl-α-D-arabino-hexopyranosid

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / OsO₄, N-methylmorpholine-N-oxide dihydrate / acetone; H₂O / 20 h / 40 °C

2: 81 percent / LiAlH₄ / diethyl ether / 0.5 h / 0 °C

With osmium(VIII) oxide; lithium aluminium tetrahydride; 4-methylmorpholine N-oxide; In diethyl ether; water; acetone;
DOI:10.1002/jlac.198619860403