CHLORO(CYCLOPENTADIENYL)[BIS(DIPHENYLPHOSPHINO)METHANE]RUTHENIUM (II)

Base Information

• Chemical Name: CHLORO(CYCLOPENTADIENYL)[BIS(DIPHENYLPHOSPHINO)METHANE]RUTHENIUM (II)
• CAS No.: 71397-33-6
• Molecular Formula: C30H27 Cl P2 Ru
• Molecular Weight: 586.015
• Mol file: 71397-33-6.mol

Synonyms:Ruthenium,chloro(h5-2,4-cyclopentadien-1-yl)[methylenebis[diphenylphosphine-kP]]- (9CI); Ruthenium, chloro(h5-2,4-cyclopentadien-1-yl)[methylenebis[diphenylphosphine]-P,P']-;Phosphine, methylenebis[diphenyl-, ruthenium complex;(Bis(diphenylphosphino)methane)(chloro)(h5-cyclopentadienyl)ruthenium; Chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium;Chlorocyclopentadienylbis(bis(diphenylphosphino)methane)ruthenium

Chemical Property of CHLORO(CYCLOPENTADIENYL)[BIS(DIPHENYLPHOSPHINO)METHANE]RUTHENIUM (II)

Chemical Property:

• Melting Point: 190-196°C
• PSA: 27.18000
• LogP: 6.92070
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

97% ^*data from raw suppliers

Chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium(II), min. 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Chloro(cyclopentadienyl)[bis(diphenylphosphino)Methane]rutheniuM(II) is a useful catalyst for the anti-Markovnikov hydration of terminal alkynes. Catalyst for:Anti-Markovnikov hydrationβ-alkylation with primary alcoholsCyclization of terminal alkynals to cycloalkenesElectrochemical oxidation of methanolHydration of 1-alkynesIsomerization of allylic alcohols

Technology Process of CHLORO(CYCLOPENTADIENYL)[BIS(DIPHENYLPHOSPHINO)METHANE]RUTHENIUM (II)

There total 3 articles about CHLORO(CYCLOPENTADIENYL)[BIS(DIPHENYLPHOSPHINO)METHANE]RUTHENIUM (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

di(rhodium)tetracarbonyl dichloride + chloro(η5-cyclopentadienyl)(triphenylphosphine)(η1-bis(diphenylphosphino)methane)ruthenium(II) → chlorocarbonylbis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium (71397-33-6)

Guidance literature:

In benzene; Ru-complex and Rh-complex were reacted in stirring benzene for 90 min under N2; solvent was removed in vac., fractional crystd. from CHCl3-light petroleum;

Reference yield: 70.0%

[(cyclopentadienyl)Ru(η6-naphthalene)]BF4 (100506-76-1) + N-benzyl-N,N,N-triethylammonium chloride (56-37-1) + bis-diphenylphosphinomethane (2071-20-7) → chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium (71397-33-6)

Guidance literature:

In dichloromethane; for 12h; Inert atmosphere;

DOI:10.1002/ejic.201201112

Reference yield:

[CpRu(η2-H2)(dppm)]OTf + trans-bis[1,2-bis(diphenylphosphino)ethane]bis(dinitrogen)tungsten(0) → chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium (71397-33-6) + Ru(H)(η(5)-cyclopentadienyl)(bis(diphenylphosphino)methane) + trans-bis[1,2-bis(diphenylphosphino)ethane]hydrazido(triflato)tungsten triflate

Guidance literature:

In 1,2-dichloro-ethane; benzene; Ru-complex was placed in flask under 1 atm of H2, dichloroethane and benzene were added, stirred at room temp. for 15 min, W-complex was added, stirred at room temp. for 24 h; evapd. under reduced pressure, trapped in H2SO4, aq. KOH was added, distilled into H2SO4;

DOI:10.1021/ic000799f

upstream raw materials:

[(cyclopentadienyl)Ru(η⁶-naphthalene)]BF₄

N-benzyl-N,N,N-triethylammonium chloride

bis-diphenylphosphinomethane

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 71397-33-6 CHLORO(CYCLOPENTADIENYL)[BIS(DIPHENYLPHOSPHINO)METHANE]RUTHENIUM (II)

Send

Send

Metric Ton KG G Pound L ML

Send

Send