Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester

Base Information

Chemical Name:Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester
CAS No.:221145-26-2
Molecular Formula:C₄₀H₄₆O₅Si
Molecular Weight:634.888
Hs Code.:

Synonyms:Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester

Suppliers and Price of Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester

There total 1 articles about Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 218271-70-6
Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-hydroxymethyl-2,3-dimethyl-cyclopentylmethyl ester

: 221145-26-2
Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; Ambient temperature;
DOI:10.1016/S0960-894X(98)00693-3

Reference yield: 83.0%

: 221145-26-2
Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester

: 221145-10-4
(1R,2R,5S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hydroxymethyl-1,2-dimethyl-cyclopentanecarboxylic acid benzyl ester

Guidance literature:: With lithium hydroxide; In tetrahydrofuran; methanol;
DOI:10.1016/S0960-894X(98)00693-3

Reference yield:

: 221145-26-2
Benzoic acid (1S,2R,3R)-2-benzyloxycarbonyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2,3-dimethyl-cyclopentylmethyl ester

: 221145-32-0
(1R,2R,5S)-2-Formyl-1,2-dimethyl-5-((3aR,4R,6R,7aS)-2,2,4-trimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yloxymethyl)-cyclopentanecarboxylic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 83 percent / aq. LiOH / methanol; tetrahydrofuran

2: BF₃*Et₂O / CH₂Cl₂

3: 78 percent / TBAF / tetrahydrofuran / Ambient temperature

4: 84 percent / PCC / CH₂Cl₂ / Ambient temperature

With lithium hydroxide; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; pyridinium chlorochromate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0960-894X(98)00693-3