4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one

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Chemical Name:4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one
CAS No.:139220-72-7
Molecular Formula:C₂₃H₂₇NO₈Si
Molecular Weight:473.555
Hs Code.:

Synonyms:4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one

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Chemical Property of 4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one

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Technology Process of 4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one

There total 3 articles about 4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 139220-44-3
5-<2,6-Diiodo-3-methoxy-5-o-nitrobenzyloxyphenoxy>-4-<2-(trimethylsilyl)eth-1-oxy>-2(5H)furanone

: 139220-73-8
6-o-Nitrobenzyloxy-4-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one

: 139220-72-7
4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one

Guidance literature:: With lithium formate; tetrabutyl-ammonium chloride; lithium carbonate; dichloro bis(acetonitrile) palladium(II); 1,3-bis-(diphenylphosphino)propane; In N,N-dimethyl-formamide; at 85 ℃; for 3h;
DOI:10.1016/S0040-4020(01)80883-8

Reference yield:

: 126680-32-8
5-bromo-4-<2-(trimethylsilyl)ethoxy>-2(5)furanone

: 139220-72-7
4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one

Guidance literature:: Multi-step reaction with 2 steps

1: 1) n-Bu₄NCl, 2) K₂CO₃ / 1) CH₂Cl₂, 2) CH₂Cl₂, H₂O, 17 h

2: 27 percent / LiOCHO, Li₂CO₃, n-Bu₄NCl / (MeCN)2PdCl₂, dppp / dimethylformamide / 3 h / 85 °C

With lithium formate; tetrabutyl-ammonium chloride; lithium carbonate; potassium carbonate; dichloro bis(acetonitrile) palladium(II); 1,3-bis-(diphenylphosphino)propane; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)80883-8

Reference yield:

: 139220-56-7
2,6-diiodo-3-methoxy-5-(2-nitrobenzyloxy)phenol

: 139220-72-7
4-o-Nitrobenzyloxy-6-methoxy-3a-<2-(trimethylsilyl)eth-1-oxy>-3a,8a-dihydrofuro<2,3-b>benzofuran-2(3H)-one

Guidance literature:: Multi-step reaction with 2 steps

1: 1) n-Bu₄NCl, 2) K₂CO₃ / 1) CH₂Cl₂, 2) CH₂Cl₂, H₂O, 17 h

2: 27 percent / LiOCHO, Li₂CO₃, n-Bu₄NCl / (MeCN)2PdCl₂, dppp / dimethylformamide / 3 h / 85 °C

With lithium formate; tetrabutyl-ammonium chloride; lithium carbonate; potassium carbonate; dichloro bis(acetonitrile) palladium(II); 1,3-bis-(diphenylphosphino)propane; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)80883-8