Pentafluorophenyl acrylate

Base Information

• Chemical Name: Pentafluorophenyl acrylate
• CAS No.: 71195-85-2
• Molecular Formula: C9H3 F5 O2
• Molecular Weight: 238.114
• Hs Code.: 29161290
• European Community (EC) Number: 690-440-5
• DSSTox Substance ID: DTXSID30379756
• Nikkaji Number: J1.021.778D
• Wikidata: Q72499827
• Mol file: 71195-85-2.mol

Synonyms:PENTAFLUOROPHENYL ACRYLATE;71195-85-2;Perfluorophenyl acrylate;(2,3,4,5,6-pentafluorophenyl) Prop-2-enoate;Pentafluorophenyl prop-2-enoate;2-Propenoic acid,2,3,4,5,6-pentafluorophenyl ester;2,3,4,5,6-pentafluorophenyl prop-2-enoate;71195-86-3;PENTAFLUOROPHENYLACRYLATE;SCHEMBL225748;DTXSID30379756;RFOWDPMCXHVGET-UHFFFAOYSA-N;Acrylic Acid Pentafluorophenyl Ester;MFCD00042330;AKOS016015624;AS-10623;CS-0121518;FT-0715546;P2179;EN300-80741;A837111;Pentafluorophenyl Acrylate (stabilized with MEHQ);Z1224459534;Pentafluorophenyl acrylate, contaning 100ppm MEHQ inhibitor;Pentafluorophenyl acrylate, contains <200 ppm monomethyl ether hydroquinone as inhibitor, 98%

Chemical Property of Pentafluorophenyl acrylate

Chemical Property:

• Vapor Pressure: 0.112mmHg at 25°C
• Refractive Index: 1.437
• Boiling Point: 145-149°C
• Flash Point: 88.6°C
• PSA: 26.30000
• Density: 1.446
• LogP: 2.47350
• Storage Temp.: 2-8°C
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 3
• Exact Mass: 238.00532014
• Heavy Atom Count: 16
• Complexity: 269

Purity/Quality:

98%,99%, ^*data from raw suppliers

PentafluorophenylAcrylate,contaning100ppmMEHQinhibitor ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OC1=C(C(=C(C(=C1F)F)F)F)F
• Uses: Pentafluorophenyl acrylate may be used in the preparation of highly porous polymers (poly HIPs). Pentafluorophenyl acrylate (PFPA) can undergo reversible addition fragmentation transfer (RAFT) polymerization with oligoethylene glycol acrylate (OEGA) or diethylene glycol acrylate (DEGA).

Technology Process of Pentafluorophenyl acrylate

There total 1 articles about Pentafluorophenyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-dimethylpyridine (108-48-5) + 2,3,4,5,6-pentafluorophenol (771-61-9) + acryloyl chloride (814-68-6,25189-84-8) → (2,3,4,5,6-pentafluorophenyl) prop-2-enoate (71195-85-2)

Guidance literature:

DMAP (4-dimethylaminopyridine); In tetrahydrofuran;

Reference yield: 85.0%

(2,3,4,5,6-pentafluorophenyl) prop-2-enoate (71195-85-2) + tert-Butyl iodide (558-17-8) → 4,4-dimethyl-pentanoic acid pentafluorophenyl ester

Guidance literature:

With air; N-ethylpiperidine hypophosphite; triethyl borane; In dichloromethane; at 0 ℃; for 0.0833333h;

DOI:10.1016/j.tetlet.2004.01.082

Reference yield: 80.0%

(2,3,4,5,6-pentafluorophenyl) prop-2-enoate (71195-85-2) + N-(1-naphthalenemethylene)-4-methoxybenzenamine (3525-60-8) → trans-1-(4-methoxy-phenyl)-3-methyl-4-(1-naphthyl)-azetidin-2-one

Guidance literature:

With triphenyl phosphite; diethylmethylsilane; chloro(1,5-cyclooctadiene)rhodium(I) dimer; at 60 ℃; for 6h;

DOI:10.1021/ol020106u

upstream raw materials:

2,6-dimethylpyridine

2,3,4,5,6-pentafluorophenol

acryloyl chloride

Downstream raw materials:

trans-3-methyl-1,4-diphenylazetidin-2-one

3-((2R,3S,4R,5R,6R)-3,4,5-Triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yl)-propionic acid pentafluorophenyl ester