3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

Base Information

Chemical Name:3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester
CAS No.:96354-43-7
Molecular Formula:C₂₈H₃₅IO₄
Molecular Weight:562.488
Hs Code.:

3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

Synonyms:3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

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Technology Process of 3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

There total 1 articles about 3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1044-90-2,1097-50-3,74015-78-4,95044-31-8,113563-82-9
(3β,5α,16α)-16,17-epoxy-3-hydroxypregnan-20-one

: 618-51-9
3-Iodobenzoic acid

: 96354-43-7
3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 20h; Ambient temperature;
DOI:10.1016/S0039-128X(84)90120-X

Reference yield:

: 96354-43-7
3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

: 3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13R,14R,16R,17S)-17-acetyl-14-chloro-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

: 96354-44-8
3-Iodo-benzoic acid (3R,5S,8S,9R,10S,13S,14S,16R,17S)-17-acetyl-9-chloro-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

Guidance literature:: With 1,2-Dichloro-3-iodobenzene; In dichloromethane; for 1h; Yields of byproduct given; Irradiation;
DOI:10.1016/S0039-128X(84)90120-X

Reference yield:

: 96354-43-7
3-Iodo-benzoic acid (3R,5S,8R,9S,10S,13S,14S,16R,17S)-17-acetyl-10,13-dimethyl-hexadecahydro-20-oxa-cyclopropa[16,17]cyclopenta[a]phenanthren-3-yl ester

: 38393-04-3
3α-Hydroxy-5α-pregna-9(11),16-dien-20-one

Guidance literature:: Multi-step reaction with 2 steps

1: 60 percent / SO₂Cl₂, benzoyl peroxide / CCl₄ / 5 h / Heating

2: 80 percent / TiCl₃-LiAlH₄ / tetrahydrofuran / 1.5 h / Heating

With lithium aluminium tetrahydride; sulfuryl dichloride; Perbenzoic acid; titanium(III) chloride; In tetrahydrofuran; tetrachloromethane;
DOI:10.1016/S0039-128X(84)90120-X