(2R,3R,4S)-4-(benzyloxy)-1-[(tert-butyldimethylsilyl)oxy]-2,5-dimethyl-3-hexanol

Base Information

Chemical Name:(2R,3R,4S)-4-(benzyloxy)-1-[(tert-butyldimethylsilyl)oxy]-2,5-dimethyl-3-hexanol
CAS No.:339570-89-7
Molecular Formula:C₂₁H₃₈O₃Si
Molecular Weight:366.616
Hs Code.:

Synonyms:(2R,3R,4S)-4-(benzyloxy)-1-[(tert-butyldimethylsilyl)oxy]-2,5-dimethyl-3-hexanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3R,4S)-4-(benzyloxy)-1-[(tert-butyldimethylsilyl)oxy]-2,5-dimethyl-3-hexanol

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Technology Process of (2R,3R,4S)-4-(benzyloxy)-1-[(tert-butyldimethylsilyl)oxy]-2,5-dimethyl-3-hexanol

There total 2 articles about (2R,3R,4S)-4-(benzyloxy)-1-[(tert-butyldimethylsilyl)oxy]-2,5-dimethyl-3-hexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 339570-88-6
(2R,4S)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-2,5-dimethyl-hexan-3-one

: 339570-89-7
(2R,3R,4S)-4-(benzyloxy)-1-[(tert-butyldimethylsilyl)oxy]-2,5-dimethyl-3-hexanol

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at -10 ℃; for 2h;
DOI:10.1021/jo001640n

Reference yield:

: 126587-67-5
(2R,3S,4S)-4-(benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-2,5-dimethyl-3-hexanol

: 339570-89-7
(2R,3R,4S)-4-(benzyloxy)-1-[(tert-butyldimethylsilyl)oxy]-2,5-dimethyl-3-hexanol

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h

2: 44 percent / LiAlH₄ / diethyl ether / 2 h / -10 °C

With lithium aluminium tetrahydride; Dess-Martin periodane; In diethyl ether; dichloromethane;
DOI:10.1021/jo001640n