[PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)]

Base Information

• Chemical Name: [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)]
• CAS No.: 1333479-72-3
• Molecular Formula: C₅₁H₄₀ClP₃PdS₂
• Molecular Weight: 951.805
• Mol file: 1333479-72-3.mol

Synonyms:[PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)]

Chemical Property of [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)]

There total 2 articles about [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[PdCl2(triphenylphosphine)]2 + 1,3-bis(diphenylthiophosphinoyl)indene (213266-62-7) → [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)] (1333479-72-3)

Guidance literature:

With HN(C₆H₁₁)2; In tetrahydrofuran; (Ar, Schlenk technique); addn. of amine deriv. to THF suspn. of palladium compd. and indene deriv. at -78°C, stirring for 10 min at -78°C, warming to room temp., stirring for 1.5 h; filtration, addn. of pentane, filtration, drying under vac., elem. anal.;

DOI:10.1039/c1dt10118h

Reference yield:

[PdCl2(triphenylphosphine)]2 + [(2)H1]1,3-bis(diphenylphosphinoyl)indene (1333479-77-8) → [PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)] (1333479-72-3)

Guidance literature:

With HN(C₆H₁₁)2; In tetrahydrofuran; (Ar, Schlenk technique); addn. of amine deriv. to THF suspn. of palladium compd. and indene deriv. at -78°C, stirring for 10 min at -78°C, warming to room temp.;

DOI:10.1039/c1dt10118h

Reference yield: 83.0%

[PdCl(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)] (1333479-72-3) → [Pd(1,3-bis(diphenylthiophosphinoyl)inden-1-yl(2-))(triphenylphosphine)]

Guidance literature:

With polystyrene supported diisopropylethylamine; In dichloromethane; (Ar, Schlenk technique); heating mixt. of palladium compd. and amine deriv. in CH2Cl2 at 35°C for 12 h; filtration, concg., addn. of pentane, filtration, drying under vac., elem. anal.;

DOI:10.1039/c1dt10118h

upstream raw materials:

1,3-bis(diphenylthiophosphinoyl)indene

[⁽²⁾H₁]1,3-bis(diphenylphosphinoyl)indene

Downstream raw materials:

[Pd(1,3-bis(diphenylthiophosphinoyl)inden-1-yl)(triphenylphosphine)](tetrafluoroborate)*CH₂Cl₂