(1S,2S,3R,5S,7R)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.0^3,5]octan-2-ol

Base Information

• Chemical Name: (1S,2S,3R,5S,7R)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.0^3,5]octan-2-ol
• CAS No.: 145661-44-5
• Molecular Formula: C₁₄H₁₆O₅
• Molecular Weight: 264.278

Synonyms:(1S,2S,3R,5S,7R)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.0^3,5]octan-2-ol

Chemical Property of (1S,2S,3R,5S,7R)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.0^3,5]octan-2-ol

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Technology Process of (1S,2S,3R,5S,7R)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.0^3,5]octan-2-ol

There total 1 articles about (1S,2S,3R,5S,7R)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.0^3,5]octan-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

phenyllithium (591-51-5) + (1R*,3S*,5R*,7S*)-6,6-dimethoxy-4,8-dioxatricyclo[5.1.0.0(3,5)]octan-2-one (84036-81-7) → (1S,2S,4S,5S,7R)-6,6-Dimethoxy-2-phenyl-3,8-dioxa-tricyclo[5.1.0.02,4]octan-5-ol (145661-45-6) + (1S,2S,3R,5S,7R)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.03,5]octan-2-ol (145661-44-5) + (1R,2R,3S,5R,7S)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.03,5]octan-2-ol (145773-07-5)

Guidance literature:

In diethyl ether; at -95 ℃;

DOI:10.1039/c39920001589

Reference yield: 66.0%

(1S,2S,3R,5S,7R)-6,6-Dimethoxy-2-phenyl-4,8-dioxa-tricyclo[5.1.0.03,5]octan-2-ol (145661-44-5) → (1R,3S,5R,6S,7S)-6-Hydroxy-6-phenyl-4,8-dioxa-tricyclo[5.1.0.03,5]octan-2-one (145661-48-9)

Guidance literature:

With Montmorillonite K₁₀; boron trifluoride diethyl etherate; In dichloromethane; for 1h; Heating;

DOI:10.1016/S0040-4039(97)00226-8

upstream raw materials:

phenyllithium

(1R*,3S*,5R*,7S*)-6,6-dimethoxy-4,8-dioxatricyclo[5.1.0.0(3,5)]octan-2-one

Downstream raw materials:

(1R,3S,5R,6S,7S)-6-Hydroxy-6-phenyl-4,8-dioxa-tricyclo[5.1.0.0^3,5]octan-2-one

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