C₂₁H₂₁Cl₆N₇O₉S

Base Information

Chemical Name:C₂₁H₂₁Cl₆N₇O₉S
CAS No.:1061574-09-1
Molecular Formula:C₂₁H₂₁Cl₆N₇O₉S
Molecular Weight:760.223
Hs Code.:

C<sub>21</sub>H<sub>21</sub>Cl<sub>6</sub>N<sub>7</sub>O<sub>9</sub>S

Synonyms:C₂₁H₂₁Cl₆N₇O₉S

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₂₁H₂₁Cl₆N₇O₉S

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Technology Process of C₂₁H₂₁Cl₆N₇O₉S

There total 10 articles about C₂₁H₂₁Cl₆N₇O₉S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 613-90-1
benzoyl cyanide

: 1061574-08-0
C₁₄H₁₇Cl₆N₇O₈S

: 1061574-09-1
C₂₁H₂₁Cl₆N₇O₉S

Guidance literature:: With dmap; In dichloromethane; acetonitrile; at -78 ℃;

Reference yield:

: 1061574-16-0
C₂₈H₃₃Cl₃N₄O₅S₂Si

: 1061574-09-1
C₂₁H₂₁Cl₆N₇O₉S

Guidance literature:: Multi-step reaction with 9 steps

1.1: 2,4,6-tri-tert-butylpyrimidine / dichloromethane / 29 h / 37 °C / Inert atmosphere; Sealed tube

2.1: ammonia / methanol / 24 h / 70 °C / Inert atmosphere; Sealed tube

3.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / -20 °C / Inert atmosphere

4.1: bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; magnesium oxide / dichloromethane / 2.5 h / 42 °C / Inert atmosphere; Sealed tube

5.1: boron trifluoride diethyl etherate; triethylsilane / dichloromethane / 1.5 h / -78 - 20 °C / Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.33 h / -78 - 0 °C / Inert atmosphere

7.1: dichloromethane / 0.25 h / -20 °C / Inert atmosphere

7.2: 12 h / Inert atmosphere

8.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; tetrahydrofuran / 12 h / Inert atmosphere

9.1: dmap / dichloromethane; acetonitrile / 1.5 h / -78 °C / Inert atmosphere

With triethylsilane; dmap; osmium(VIII) oxide; bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; ammonia; magnesium oxide; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; 2,4,6-tri-tert-butylpyrimidine; In tetrahydrofuran; methanol; dichloromethane; water; acetonitrile;
DOI:10.1021/jacs.6b02343

Reference yield:

: 1061574-11-5
C₉H₁₂N₂O₄

: 1061574-09-1
C₂₁H₂₁Cl₆N₇O₉S

Guidance literature:: Multi-step reaction with 13 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 14 h / 0 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / dichloromethane; toluene / 2 h / -90 °C / Inert atmosphere

3.1: dichloromethane / 0.33 h / 0 - 20 °C / Inert atmosphere

3.2: 1.67 h / -78 - 20 °C / Inert atmosphere

4.1: 1,3-dimethylbarbituric acid; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / dichloromethane / 8 h / Inert atmosphere

4.2: 0.33 h / Inert atmosphere

5.1: 2,4,6-tri-tert-butylpyrimidine / dichloromethane / 29 h / 37 °C / Inert atmosphere; Sealed tube

6.1: ammonia / methanol / 24 h / 70 °C / Inert atmosphere; Sealed tube

7.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / -20 °C / Inert atmosphere

8.1: bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; magnesium oxide / dichloromethane / 2.5 h / 42 °C / Inert atmosphere; Sealed tube

9.1: boron trifluoride diethyl etherate; triethylsilane / dichloromethane / 1.5 h / -78 - 20 °C / Inert atmosphere

10.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.33 h / -78 - 0 °C / Inert atmosphere

11.1: dichloromethane / 0.25 h / -20 °C / Inert atmosphere

11.2: 12 h / Inert atmosphere

12.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; tetrahydrofuran / 12 h / Inert atmosphere

13.1: dmap / dichloromethane; acetonitrile / 1.5 h / -78 °C / Inert atmosphere

With 1H-imidazole; triethylsilane; dmap; osmium(VIII) oxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 1,3-dimethylbarbituric acid; bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; ammonia; magnesium oxide; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; 2,4,6-tri-tert-butylpyrimidine; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 3.1: |Pictet-Spengler Synthesis / 3.2: |Pictet-Spengler Synthesis;
DOI:10.1021/jacs.6b02343