1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose

Base Information

Chemical Name:1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose
CAS No.:821005-74-7
Molecular Formula:C₄₇H₅₀O₉S
Molecular Weight:790.975
Hs Code.:

Synonyms:1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose

Suppliers and Price of 1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose

There total 4 articles about 1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (1R,3S,4R,5R)-3-[(R)-Hydroxy-((2S,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-methyl]-4-phenylsulfanyl-6,8-dioxa-bicyclo[3.2.1]octan-2-one

: 821005-74-7
1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose

Guidance literature:: With sodium tetrahydroborate; In methanol; at 0 ℃; for 2h;
DOI:10.1016/j.tetasy.2004.09.029

Reference yield:

: 140397-46-2
(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)methanal

: 821005-74-7
1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 73 percent / Et₂AlI / toluene; CH₂Cl₂ / 19 h / -80 °C

2: triethylamine / CH₂Cl₂ / 1 h / 0 °C

3: 1.33 g / NaBH₄ / methanol / 2 h / 0 °C

With sodium tetrahydroborate; diethylaluminum iodide; triethylamine; In methanol; dichloromethane; toluene; 1: Oshima-Nozaki condensation;
DOI:10.1016/j.tetasy.2004.09.029

Reference yield:

: 33647-85-7
isolevoglucosenone

: 821005-74-7
1,6-anhydro-3-C-[(1R)-2,6-anhydro-3,4,5,7-tetra-O-benzyl-D-glycero-L-manno-heptitol-1-C-yl]-2,3-dideoxy-2-phenylthio-β-D-galacto-pyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 73 percent / Et₂AlI / toluene; CH₂Cl₂ / 19 h / -80 °C

2: triethylamine / CH₂Cl₂ / 1 h / 0 °C

3: 1.33 g / NaBH₄ / methanol / 2 h / 0 °C

With sodium tetrahydroborate; diethylaluminum iodide; triethylamine; In methanol; dichloromethane; toluene; 1: Oshima-Nozaki condensation;
DOI:10.1016/j.tetasy.2004.09.029