4-(trimethylsilyloxy)cyclohex-1-en-1-yl nonaflate

Base Information

• Chemical Name: 4-(trimethylsilyloxy)cyclohex-1-en-1-yl nonaflate
• CAS No.: 1353042-69-9
• Molecular Formula: C₁₃H₁₇F₉O₄SSi
• Molecular Weight: 468.413
• Mol file: 1353042-69-9.mol

Synonyms:4-(trimethylsilyloxy)cyclohex-1-en-1-yl nonaflate

Chemical Property of 4-(trimethylsilyloxy)cyclohex-1-en-1-yl nonaflate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 4-(trimethylsilyloxy)cyclohex-1-en-1-yl nonaflate

There total 2 articles about 4-(trimethylsilyloxy)cyclohex-1-en-1-yl nonaflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

Nonafluorobutanesulfonyl fluoride (375-72-4) + 1,4-bis(trimethylsilyloxy)cyclohex-1-ene (6838-67-1) → 4-(trimethylsilyloxy)cyclohex-1-en-1-yl nonaflate (1353042-69-9)

Guidance literature:

With potassium fluoride; dibenzo-18-crown-6; In hexane; dimethyl sulfoxide; at 20 ℃; for 22h; Inert atmosphere;

DOI:10.1055/s-0030-1260207

Reference yield:

4-hydroxycyclohexanone (13482-22-9) → 4-(trimethylsilyloxy)cyclohex-1-en-1-yl nonaflate (1353042-69-9)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine; sodium iodide / acetonitrile / -30 - 20 °C / Inert atmosphere

2: potassium fluoride; dibenzo-18-crown-6 / hexane; dimethyl sulfoxide / 22 h / 20 °C / Inert atmosphere

With potassium fluoride; dibenzo-18-crown-6; triethylamine; sodium iodide; In hexane; dimethyl sulfoxide; acetonitrile;

DOI:10.1055/s-0030-1260207

upstream raw materials:

Nonafluorobutanesulfonyl fluoride

1,4-bis(trimethylsilyloxy)cyclohex-1-ene

4-hydroxycyclohexanone