2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole

Base Information

Chemical Name:2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole
CAS No.:616895-64-8
Molecular Formula:C₂₂H₃₅NO₃S₂Si
Molecular Weight:453.742
Hs Code.:

Synonyms:2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole

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Chemical Property of 2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole

Chemical Property:

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Technology Process of 2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole

There total 1 articles about 2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 616895-64-8
2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole

Guidance literature:: Multi-step reaction with 5 steps

1: 99 percent / Et₃N / CH₂Cl₂ / 0 °C

2: 98 percent / NaHMDS / tetrahydrofuran / 0 °C

3: 89 percent / BH₃*NH₃; LDA / tetrahydrofuran

4: PPh₃; DEAD / tetrahydrofuran

5: MCPBA / CH₂Cl₂

With borane-ammonia complex; sodium hexamethyldisilazane; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium diisopropyl amide; diethylazodicarboxylate; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4020(03)00370-3

Reference yield:

: 256397-91-8
[2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]aldehyde

: 616895-64-8
2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole

: {(2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-[(E)-2-((1S,2S,3S)-2-methyl-3-triisopropylsilanyloxymethyl-cyclopropyl)-vinyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester

Guidance literature:: With sodium hexamethyldisilazane; In N,N-dimethyl-formamide; at -45 - 20 ℃;
DOI:10.1016/S0040-4020(03)00370-3

Reference yield:

: 616895-64-8
2-((1S,2R,3S)-2-Methyl-3-triisopropylsilanyloxymethyl-cyclopropylmethanesulfonyl)-benzothiazole

: 153618-43-0
{(2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-[(E)-2-((1S,2S,3S)-2-hydroxymethyl-3-methyl-cyclopropyl)-vinyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: NaHMDS / dimethylformamide / -45 - 20 °C

2: TsOH / methanol

With sodium hexamethyldisilazane; toluene-4-sulfonic acid; In methanol; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(03)00370-3