(Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester

Base Information

Chemical Name:(Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester
CAS No.:159684-42-1
Molecular Formula:C₂₂H₂₄O₄S₂
Molecular Weight:416.562
Hs Code.:

Synonyms:(Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester

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Chemical Property of (Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester

Chemical Property:

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Technology Process of (Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester

There total 1 articles about (Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 1-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-bis-phenylsulfanyl-ethanone

: (Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4-phenylsulfanyl-but-2-enoic acid methyl ester

: (E)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester

: 159684-42-1
(Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester

Guidance literature:: With benzoic acid; In benzene; for 24h; Heating;
DOI:10.1016/0040-4039(94)85305-3

Reference yield: 90.0%

: 159684-42-1
(Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester

: (Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; diethyl ether; at 0 ℃; for 0.5h;
DOI:10.1016/0040-4039(94)85305-3

Reference yield:

: 159684-42-1
(Z)-3-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-4,4-bis-phenylsulfanyl-but-2-enoic acid methyl ester

: 2,2-Dimethyl-4-(2-phenylsulfanyl-furan-3-yl)-[1,3]dioxolane

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / 1.0M DIBAL-H / tetrahydrofuran; diethyl ether / 0.5 h / 0 °C

2: 98 percent / NaH / tetrahydrofuran / 3 h / Ambient temperature

3: 54 percent / iodine / acetone / 2 h / Ambient temperature

With iodine; sodium hydride; diisobutylaluminium hydride; In tetrahydrofuran; diethyl ether; acetone;
DOI:10.1016/0040-4039(94)85305-3